Sidearm effects in the enantioselective cyclopropanation of alkenes with aryldiazoacetates catalyzed by trisoxazoline/Cu(I)

A highly enantioselective cyclopropanation of alkenes with phenyldiazoacetates catalyzed by CuPF6(CH3CN)(4)/trisoxazoline has been developed.

Saved in:
Bibliographic Details
Published inChemical communications (Cambridge, England) no. 19; pp. 1960 - 1962
Main Authors Xu, Zheng-Hu, Zhu, Sha-Na, Sun, Xiu-Li, Tang, Yong, Dai, Li-Xin
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2007
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
ORGANIC-SYNTHESIS
DIRHODIUM(II)
LIGANDS
RAY CRYSTAL-STRUCTURES
COMPLEXES
ASYMMETRIC MICHAEL ADDITION
OLEFINS
DIAZO-COMPOUNDS
SELECTIVITY
CHIRAL CATALYSTS
Online AccessGet more information

Cover

More Information
Summary:A highly enantioselective cyclopropanation of alkenes with phenyldiazoacetates catalyzed by CuPF6(CH3CN)(4)/trisoxazoline has been developed.
ISSN:1359-7345
1364-548X
DOI:10.1039/b617967c