Temperature dependence of the Casimir-like force in free-standing smectic films

• Published in: Physical review. E, Statistical, nonlinear, and soft matter physics Vol. 73; no. 4 Pt 1; p. 041703
• Main Authors: de Oliveira, I N, Lyra, M L, Mirantsev, L V
• Format: Journal Article
• Language: English
• Published: United States 01.04.2006
• ISSN: 1539-3755
• DOI: 10.1103/PhysRevE.73.041703

The thermal Casimir-like force in free-standing liquid crystal films close to the smectic-A-nematic transition temperature is computed using a quadratic functional approach. In the framework of a microscopic mean-field model of free-standing smectic-A films, the temperature dependence of the order parameter profiles is computed and later used to estimate the elastic coupling variability in the vicinity of first- and second-order bulk smectic-A-nematic phase transitions. The strong nonuniformity of the coupling constant profiles promotes a significant increase of the fluctuation-induced force over three orders of magnitude, especially in thin films. This result reinforces the possible predominance of the thermal Casimir force as compared to the standard van der Waals interaction in thin smectic-A liquid crystal films.