Three bond modes of basic refractories used for Ruhrstahl Heraeus degassing process

• Published in: Journal of the American Ceramic Society Vol. 106; no. 9; pp. 5403 - 5419
• Main Authors: Guo, Zongqi, Dai, Yajie, Chen, Jiahui, Lei, Zhongxing, Gao, Jianying, Yuan, Wenjie
• Format: Journal Article
• Language: English
• Published: Columbus Wiley Subscription Services, Inc 01.09.2023
• Subjects: Aluminum; Basic refractories; bond mode; Bricks; Chemical reactions; Chromite; Chromium; Corrosion resistance; Degassers; Degassing; Flexibility; fracture mechanism; Germination; Heating; High temperature; Magnesium oxide; Periclase; Phase transitions; Physical properties; RH degassing process; Shock resistance; Sintering (powder metallurgy); Slag; Spinel; Thermal resistance; Thermal shock; whisker network; Whiskers (metals)
• ISSN: 0002-7820; 1551-2916
• DOI: 10.1111/jace.19148

Magnesia–spinel brick and unburnt periclase–spinel–Al brick are being employed as a substitution of traditional magnesia–chrome brick in the chromium‐free campaign of lining materials in Ruhrstahl Heraeus (RH) degasser. These three materials are investigated, in terms of physical properties, corrosion resistance and flexibility by wedge splitting test. Tracking their physical alterations and chemical reactions through burning or heating, three bond modes are discovered. Magnesia–chrome brick is subject to a series of phase transformation with rising temperature to yield a liquid envelop around chromite‐ore particles, to further form porous rim while liquid is gradually absorbed by surrounding magnesia and eventually to precipitate secondary chromite spinel lied between magnesia particles by thoroughly dissociating chrome ore. The precipitated chromite spinel functions as the featured bond that enhances hot strength and corrosion resistance to slag, and additionally liquid coexistence improves the flexibility. The direct bond mode of magnesia particles in magnesia–spinel brick endures slag penetration by immanent character of MgO. Spinel incorporation in magnesia effectively improves thermal shock resistance. Due to minor negative value of permanent linear change after reheating, further sintering (densifying) in using at high temperature would bring a risk of loosening and open joints of magnesia–spinel lining. While used in RH degasser, unburnt periclase–spinel–Al bricks undergo a miraculous process of metallic Al melting, gaseous AlN and AlON formation, MgAlON whiskers germination combined with gaseous Mg reduced, and micron‐size whisker network bond domination in their matrix. Such a whisker‐network bond renders the material a successful eco‐friendly alternative to magnesia–chrome refractory.