Available surface electronic transmission of porous SnO2/NiO hollow nanofibers for the enhanced gas-sensing performance toward n-butanol

• Published in: Materials science in semiconductor processing Vol. 128; p. 105762
• Main Authors: Ma, Qian, Li, Hang, Guo, Jia, Chu, Shushu, Zhang, Qi, Lin, Ziqiong
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 15.06.2021
• Subjects: Electrospinning; Gas sensor; n-butanol; Porous; SnO2/NiO; Electrospinning; n-butanol; Gas sensor; SnO2/NiO; Porous
• ISSN: 1369-8001; 1873-4081
• DOI: 10.1016/j.mssp.2021.105762

Porous SnO2/NiO hollow nanofibers with effective surface transmission behavior have been prepared through a facile modified electrospinning method. The introduction of Ni component into the precursor solution can not only regulate the morphological evolution together with the nucleation and crystallization of oxide heterostructures at the elevated temperature action, but also significantly contribute to the enhancement of the gas-sensing performance for testing n-butanol gas. SnO2/NiO composites can present the highest response of 199 at the optimum operating temperature of 280 °C toward 100 ppm n-butanol gas, which is 4.5 times than that of pure SnO2 nanofibers. Meanwhile, the response/recovery times of the sensors can be immensely decreased from 57/16 s of pure sample to 36/10 s as the adding amount of Ni component increasing to 5%, along with the superior selectivity and long-term stability toward n-butanol. The excellent gas-sensing properties of the sensors can be mainly attributed to the flourishing porous one-dimensional (1D) microstructure containing the closely connected p-n heterojunctions of SnO2 and NiO, which can provide large specific surface areas with a mass of active sites to promote the reaction between n-butanol molecule and Oδ− on the surface. [Display omitted] •Porous SnO2/NiO hollow nanofibers were gained by a facile electrospinning method.•The introduction of Ni component regulates the morphological evolution of samples.•SnO2/NiO nanofibers show the excellent gas-sensing performance to n-butanol.•High response, rapid response/recovery times, and good stability can be obtained.•The mechanism is due to the p-n heterojunction and tunable porous microstructure.