Pd-doped lanthanum ferrites for symmetric solid oxide fuel cells (SSOFCs)

• Published in: Materialia Vol. 8; p. 100460
• Main Authors: Marcucci, Andrea, Zurlo, Francesca, Sora, Isabella Natali, Luisetto, Igor, Licoccia, Silvia, Bartolomeo, Elisabetta Di
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.12.2019
• Subjects: Electrochemical impedance spectroscopy; Fuel cell tests; Perovskite; Ruddlesden-Popper phase; Symmetric solid oxide fuel cell (SSOFC); Perovskite; Symmetric solid oxide fuel cell (SSOFC); Ruddlesden-Popper phase; Fuel cell tests; Electrochemical impedance spectroscopy
• ISSN: 2589-1529; 2589-1529
• DOI: 10.1016/j.mtla.2019.100460

Pd-doped lanthanum strontium ferrite powders La0.6Sr0.4Fe1-xPdxO3-δ with x = 0.05, 0.1 (LSFPd05 and LSFPd10) are synthesized by combustion synthesis method and investigated as electrocatalysts for fuel and air electrodes of symmetric solid oxide fuel cells (SSOFCs). X-ray diffraction (XRD), Rietveld refinement, surface area (BET), temperature programmed reaction (TPR) and temperature programmed oxidation (TPO) analyses are performed on LSFPd powders. Electrical measurements both in oxidizing and reducing conditions are carried out on sintered pellets. Electrolyte (La0.8Sr0.2Ga0.8Mg0.2O3-δ) supported cells are prepared using LSFPd powders as electrodes. The electrochemical performances are evaluated in hydrogen and methane mixtures and promising performance are revealed in terms of large power output density and low polarization resistance. [Display omitted]