Enhanced accumulation of bitumen residue in a highly concentrated tailings flow by microbubbles from in-situ catalytic decomposition of hydrogen peroxide

• Published in: Fuel (Guildford) Vol. 345; p. 128249
• Main Authors: Zhou, Kaiyu, Sontti, Somasekhara Goud, Zhou, Joe, Zhang, Xuehua
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.08.2023
• Subjects: H2O2 decomposition; High-speed camera; Microbubbles; Oil sands tailings; Pipeline loop; Microbubbles; Oil sands tailings; H2O2 decomposition; High-speed camera; Pipeline loop
• ISSN: 0016-2361; 1873-7153
• DOI: 10.1016/j.fuel.2023.128249

The massive volume of oil sands tailings has been one of the most challenging environmental issues. In this work, we experimentally explore a simple and effective approach to bitumen residue separation from a highly concentrated slurry flow of the artificial oil sands tailings. By utilizing microbubbles from in-situ catalytic decomposition of H2O2 at low concentrations, bitumen aggregation is enhanced on the top part of the hydrotransport pipeline. The microscopic image analysis revealed the in-situ formation of microbubbles and confirmed that magnetic particles present in the slurries contributed to the fast release of the gas products and bubble formation from hydrogen peroxide decomposition. A high-speed camera was applied to capture images of the tailings flow in the pipeline through a transparent view window. A large number of tiny bubbles were identified post to the injection of H2O2 to the slurry flow. More than 70 % bitumen could be recovered from a lab-scale pipeline loop within 30 mins after H2O2 injection. The bitumen recovery efficiency from the collected froth was quantitatively compared under seven conditions with varied dosages, the concentration of H2O2, and the amount of magnetic solids in the slurries. Our results confirmed that the total dosage of H2O2 is the dominant factor in in-situ microbubble formation for enhanced bitumen aggregation in the flow. Importantly, microbubbles were generated rapidly in the real mature fine tailings. The results from our study provide insights into the preferential distribution of oil residue in the flow during hydrotransport without the requirement for an additional device. Removal of oily residues from concentrated slurries may bring economical and environmental advantages. [Display omitted] •Prior to tailings disposal, bitumen recovery is crucial to reduce GHG emission.•Microbubble-based technology is developed for bitumen residue separation.•Microbubbles spontaneously form by addition of H2O2 in tailings.•Intrinsic magnetic mineral particles in tailings catalyze decomposition of H2O2.•Achieve >70% recovery efficiency by controlled addition of a small volume of H2O2.