The promotion of NH3-SCR performance and its mechanism on Sm modified birnessite

• Published in: Fuel (Guildford) Vol. 356; p. 129604
• Main Authors: Wang, Jiawang, Xie, Heng, Shu, Daobing, Chen, Tianhu, Liu, Haibo, Zou, Xuehua, Chen, Dong
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 15.01.2024
• Subjects: Birnessite; Low-temperature denitrification; NH3-SCR; Sm/Mn; Birnessite; NH3-SCR; Low-temperature denitrification; Sm/Mn
• ISSN: 0016-2361
• DOI: 10.1016/j.fuel.2023.129604

•Highly active Sm/Mn catalysts were prepared at low temperature (150 °C).•0.05Sm/Mn catalyst achieved 100% NOX conversion at low temperatures (<50 °C).•Sm doping promoted the acidic sites on the Sm/Mn catalyst surface.•The introduction of Sm improved low temperature H2O/SO2 resistance of catalysis. To develop novel NH3-SCR catalysts with low-temperature and high-efficency, a series of birnessite (δ-MnO2) catalysts with different Sm doping by methanol reduction are synthesized. The results showed that the introduction of Sm successfully inhibited the crystallization of MnOX, promoted the specific surface area, the contents of chemisorbed oxygen species and the formation of surface acid sites. It also increased the relative content of (Mn4+ + Mn3+)/Mn, which was beneficial to low-temperature SCR activity. The catalytic performance of xSm/Mn (δ-MnO2 based with xSm doping) catalysts was evaluated by NH3-SCR performances. Among them, 0.05 Sm/Mn showed 100% NOX conversion and high N2 selectivity compared to the other Sm addition catalysts within the operating low-temperature window (25–200 °C), at a high GHSV (gas hourly space velocity) of 60,000 h−1. The modified 0.05 Sm/Mn catalysts followed the L-H and E-R reaction mechanisms and were dominated by L-H, as revealed by in-situ DRIFTs analysis.