Highly interpenetrated diamondoid nets of Zn( ii ) and Cd( ii ) coordination networks from mixed ligands

The syntheses, structures and thermal properties of three coordination networks [Zn(L super(1))(1,4-BDC)].H sub(2)O (L super(1) = N,N'-di(4-pyridyl)adipoami de; 1,4-H sub(2)BDC = 1,4-benzenedicarboxylic acid), 1, [Cd(L super(1))(1,4-BDC)].2H sub(2)O, 2, and [Zn sub(2)(L super(2))(1,4-BDC) sub(2...

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Published inCrystEngComm Vol. 14; no. 2; pp. 537 - 543
Main Authors Cheng, Jian-Jr, Chang, Ya-Ting, Wu, Chia-Jun, Hsu, Yi-Fen, Lin, Chia-Her, Proserpio, Davide M., Chen, Jhy-Der
Format Journal Article
LanguageEnglish
Published 01.01.2012
Subjects
Diamonds
Dimers
Interpenetrating networks
Ligands
Networks
Spacers
Thermal properties
Topology
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Summary:The syntheses, structures and thermal properties of three coordination networks [Zn(L super(1))(1,4-BDC)].H sub(2)O (L super(1) = N,N'-di(4-pyridyl)adipoami de; 1,4-H sub(2)BDC = 1,4-benzenedicarboxylic acid), 1, [Cd(L super(1))(1,4-BDC)].2H sub(2)O, 2, and [Zn sub(2)(L super(2))(1,4-BDC) sub(2)].2CH sub(3)OH (L super(2) = N,N'-di(4-pyridyl)dodecana mide), 3, are reported. Complexes 1 and 2 show the dia topology with the rare 8- and 9-fold interpenetrating modes, respectively, while 3 exhibits an interpenetrating 3-fold framework with the pcu Zn sub(2)(COO) sub(2) dimer decorated topology. Complex 2 shows the maximum number of interpenetration presently known for interpenetrating diamondoid networks of coordination networks containing mixed spacer ligands.
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ISSN:1466-8033
1466-8033
DOI:10.1039/C1CE06019H