The effect of pretreatment on methanesulfonic acid-catalyzed hydrolysis of bagasse to levulinic acid, formic acid, and furfural

A major challenge that must be overcome for the commercial production of levulinic acid from lignocellulosics is to reduce equipment blockage and corrosion. Methanesulfonic acid (MSA), a relatively low corrosive acid, was used to produce organic acids and furfural from pretreated sugarcane bagasse....

Full description

Saved in:
Bibliographic Details
Published inRSC advances Vol. 6; no. 78; pp. 74525 - 74535
Main Authors Rackemann, Darryn W., Bartley, John P., Harrison, Mark D., Doherty, William O. S.
Format Journal Article
LanguageEnglish
Published 01.01.2016
Subjects
Bagasse
Blockage
Fatty acids
Formic acid
Furfural
Hydrolysis
Lignocellulose
Pretreatment
Online AccessGet full text

Cover

More Information
Summary:A major challenge that must be overcome for the commercial production of levulinic acid from lignocellulosics is to reduce equipment blockage and corrosion. Methanesulfonic acid (MSA), a relatively low corrosive acid, was used to produce organic acids and furfural from pretreated sugarcane bagasse. In general, the type of pretreatment did not affect levulinic acid yield, though it affected furfural yield. However, soda pretreated bagasse produced the highest yields of levulinic acid ( similar to 75 mol%) and furfural ( similar to 85 mol%), albeit under optimized conditions. Hydrolysis residue consists primarily of lignin that has been modified and/or condensed to humic substances, fatty acids, and oligomeric sugars. A conceptual biorefinery utilizing 1 ton of dry bagasse, alkaline-pretreatment, and MSA as a catalyst produced 165 kg soda lignin, 190 kg and 89 kg of levulinic acid and formic acid respectively, and 40 kg furfural.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:2046-2069
2046-2069
DOI:10.1039/C6RA14772K