Radial vibration of ultra-small nanoparticles with surface effects

• Published in: The Journal of physics and chemistry of solids Vol. 85; pp. 287 - 292
• Main Authors: Wang, Jianbiao, Gao, Yuanwen, Ng, Ming-Yaw, Chang, Yia-Chung
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.10.2015
• Subjects: Mechanical properties; Nanostructures; Raman spectroscopy; Surfaces; Surfaces; Mechanical properties; Nanostructures; Raman spectroscopy
• ISSN: 0022-3697; 1879-2553
• DOI: 10.1016/j.jpcs.2015.06.005

An elastic model to predict radial vibration of ultra-small nanoparticles is proposed and the main reason of frequency shifts (comparing with classical elastic model) in ultra-small nanoparticles is interpreted. Taking the curvature-dependent surface theory into account, the effects of surface on the radial vibrations of nanoparticles are investigated with our new model. Both the atomic and the present models are calculated and their results agree well. It argues that the surface effects are remarkable on the radial vibrations of ultra-small nanoparticles and surface elasticity plays the main role rather than surface stress which is the previous understanding. The curvature-dependence of surface effects cannot be ignored when the particle is small enough. For the low-order radial vibration, the surface effects are more noteworthy. •The reason of radial frequency shifts in nanoparticles is found.•Size-dependence of nanoparticles’ radial vibration is clarified.•It provides an interpretation of higher order radial vibration.