Structure and Optical Activity in Metal Complexes, VI. Interaction of Histidine with Copper(II) in Solution

The species existing in aqueous solution at pH 8.3 when copper(II) interacts with two equivalents of L-histidine has been studied by a variety of techniques. The evidence is consistent with a fluctuating type of coordination for the histidinato-copper(II) complex, which varies according to condition...

Full description

Saved in:
Bibliographic Details
Published inProceedings of the National Academy of Sciences - PNAS Vol. 64; no. 3; pp. 824 - 827
Main Authors Wellman, Keith M., Wong, Boon-Khin
Format Journal Article
LanguageEnglish
Published United States National Academy of Sciences of the United States of America 01.11.1969
National Acad Sciences
Subjects
Amino acids
Dichroism
Esters
Histamines
Ligands
Mathematical constants
Physical Sciences: Chemistry
Red shift
Wavelengths
Online AccessGet full text

Cover

More Information
Summary:The species existing in aqueous solution at pH 8.3 when copper(II) interacts with two equivalents of L-histidine has been studied by a variety of techniques. The evidence is consistent with a fluctuating type of coordination for the histidinato-copper(II) complex, which varies according to conditions and other coordinating ligands involved.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
Part V: Wellman, K. M., Bogdansky, C. Piontek, C. R. Hare, and M. Mathiesson, Inorg. Chem., 8, 1025 (1969).
ISSN:0027-8424
1091-6490
DOI:10.1073/pnas.64.3.824