Rhodium catalysed addition of boronic acids to anhydrides: a new method for the synthesis of ketones

The efficient transmetalation from boron to rhodium is exploited in a new synthesis of aryl and alkenyl ketones.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 22; pp. 2316 - 2317
Main Authors Frost, CG, Wadsworth, KJ
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 21.11.2001
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
ORGANOBORONIC ACIDS
CHLORIDES
ENONES
ALDEHYDES
1,4-ADDITION
ARYLBORONIC ACIDS
CONJUGATE ADDITION
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Summary:The efficient transmetalation from boron to rhodium is exploited in a new synthesis of aryl and alkenyl ketones.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1359-7345
1364-548X
DOI:10.1039/b107633g