One- and three-dimensional infinite arrays of Cu(I) ions exhibited by [Cu(NH3)2]Br and [Cu(NH3)Cl] in the solid state

In the solid state, [Cu(NH3)Cl] forms a three-dimensional network with each Cu(I) ion being surrounded by three other Cu(I) centres in a trigonal-planar fashion [Cu...Cu = 2.979(1) A; cubic space group I2(1)3], whereas in [Cu(NH3)2]Br the cations establish infinite linear (Cu...Cu) chains spanning t...

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Published inChemical communications (Cambridge, England) no. 8; pp. 956 - 957
Main Authors Margraf, Günter, Bats, Jan W, Bolte, Michael, Lerner, Hans-wolfram, Wagner, Matthias
Format Journal Article
LanguageEnglish
Published England 01.01.2003
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Summary:In the solid state, [Cu(NH3)Cl] forms a three-dimensional network with each Cu(I) ion being surrounded by three other Cu(I) centres in a trigonal-planar fashion [Cu...Cu = 2.979(1) A; cubic space group I2(1)3], whereas in [Cu(NH3)2]Br the cations establish infinite linear (Cu...Cu) chains spanning the crystal lattice [Cu...Cu = 2.931(1) A; monoclinic space group C2/c].
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1359-7345
1364-548X
DOI:10.1039/b212517j