Synthesis and performance evaluation of binuclear metal phthalocyanines as high-efficiency electrocatalysts for Li/SOCl2 batteries

• Published in: Journal of materials research Vol. 33; no. 16; pp. 2376 - 2384
• Main Authors: Su, Yuanyuan, Zhang, Ying, Zhang, Ronglan, Yang, Fei, Zhao, Jianshe
• Format: Journal Article
• Language: English
• Published: New York, USA Cambridge University Press 28.08.2018; Springer International Publishing; Springer Nature B.V
• Subjects: Applied and Technical Physics; Aviation; Batteries; Biomaterials; Carbon; Catalysis; Chemical synthesis; Chloride; Cobalt; Coordination compounds; Copper; Discharge; Electrocatalysts; Electrodes; Electrolytes; Infrared spectroscopy; Inorganic Chemistry; Kerosene; Lithium; Manganese ions; Materials Engineering; Materials research; Materials Science; Metal ions; Metal phthalocyanines; Nanotechnology; Performance evaluation; Photocatalysis; Work stations; United States > US; Connecticut; lithium/thionyl chloride battery; catalytic mechanism; binuclear metal phthalocyanines; catalytic performances
• ISSN: 0884-2914; 2044-5326
• DOI: 10.1557/jmr.2018.238

Two series of binuclear metal phthalocyanine complexes M2(PcTN)2Nap and M2(PcTA)2Nap (M = Mn2+, Fe2+, Co2+, Cu2+) were designed and synthesized through the liquid solvent method and amination reaction. Elemental analysis, IR, and UV-vis spectroscopy were applied to characterize the compounds. To evaluate their catalytic performance, all the compounds were respectively added into the electrolyte of Li/SOCl2 battery systems as well as three-electrode systems for cyclic voltammetry (CV) measurements. The research studies indicate that the average discharge voltage and discharge time of the battery could be effectively enhanced by 0.2440 V and 810.7 s when compared with the battery in the absence of the compounds. As for capacities of the batteries containing catalysts, they were also found to have an improvement of 51.78–91.62%. Among the effects of diverse metal ions on the catalytic performance of phthalocyanines, the complexes whose center metal ions were Mn2+ or Co2+ exhibited relatively high catalytic performance. Meanwhile, combined with experimental results of CV analyses, the suggested catalytic mechanism of binuclear phthalocyanines for catalyzing Li/SOCl2 batteries had been proposed.