Regio- and enantioselective iridium-catalysed allylic aminations and alkylations of dienyl esters

Regio- and enantioselective iridium-catalysed allylic aminations and alkylations of dienyl substrates are presented; using phosphorus amidite L1 as ligand, aminations provided ee values of up to 97% and alkylations of up to 90%.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 1; pp. 116 - 117
Main Authors Lipowsky, G, Helmchen, G
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 07.01.2004
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
SUBSTITUTION
ASYMMETRIC-SYNTHESIS
REAGENTS
LIGANDS
COMPLEXES
ACETATES
PHOSPHORUS AMIDITES
CONJUGATE ADDITION
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Summary:Regio- and enantioselective iridium-catalysed allylic aminations and alkylations of dienyl substrates are presented; using phosphorus amidite L1 as ligand, aminations provided ee values of up to 97% and alkylations of up to 90%.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1359-7345
1364-548X
DOI:10.1039/b311502j