Highly saddle shaped (porphyrinato) iron(III) iodide with a pure intermediate spin state

Combined analyses using NMR, EPR and Mossbauer spectroscopy as well as SQUID magnetometry have revealed that highly saddle shaped Fe(OETPP) I adopts an essentially pure intermediate spin state in spite of the coordination of an iodide ligand.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 11; pp. 1198 - 1199
Main Authors Nakamura, M, Ikeue, T, Ohgo, Y, Takahashi, M, Takeda, M
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 07.06.2002
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
2,3,7,8,12,13,17,18-OCTAETHYL-5,10,15,20-TETRAPHENYLPORPHYRIN
S=3/2
PERCHLORATE
COMPLEXES
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Summary:Combined analyses using NMR, EPR and Mossbauer spectroscopy as well as SQUID magnetometry have revealed that highly saddle shaped Fe(OETPP) I adopts an essentially pure intermediate spin state in spite of the coordination of an iodide ligand.
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ISSN:1359-7345
1364-548X
DOI:10.1039/b202768b