N-heterocyclic carbenes can coexist with alkenes and C-H acidic sites

The isolation of compounds 3 and 7a, b proves that a singlet carbene center can coexist with alkenes or C-H acidic sites in proximity without spontaneous annihilation.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 21; pp. 2240 - 2241
Main Authors Furstner, A, Krause, H, Ackermann, L, Lehmann, CW
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2001
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
COUPLING REACTIONS
ARYL CHLORIDES
CATALYSTS
STABLE CARBENES
COMPLEXES
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Summary:The isolation of compounds 3 and 7a, b proves that a singlet carbene center can coexist with alkenes or C-H acidic sites in proximity without spontaneous annihilation.
Bibliography:ObjectType-Article-1
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ObjectType-Feature-2
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ISSN:1359-7345
1364-548X
DOI:10.1039/b107238b