Chelate complexes from diphosphine substitution in pentakis(arylisocyanide)cobalt(I) complexes
Four chelate complexes, [Co(CNC 6 H 3 iPr 2 -2,6) 3 P(C 6 H 4 Me-p) 2 CH 2 CH 2 P(C 6 H 4 Me-p) 2 ]BF 4 , [Co(CNC 6 H 3 iPr 2 -2,6) 3 PPh 2 CH=CHPPh 2 -cis]BF 4 , [Co(CNC 6 H 3 iPr 2 -2,6) 3 PPh 2 C 6 H 4 PPh 2 -o]BF 4 , and [Co(CNC 6 H 3 iPr 2 -2,6) 3 P(C 6 H 4 CF 3 -p) 2 CH 2 CH 2 P(C 6 H 4 CF 3 -...
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| Published in | Journal of coordination chemistry Vol. 60; no. 2; pp. 153 - 161 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Taylor & Francis Group
20.01.2007
|
| Subjects | |
| Online Access | Get full text |
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| Abstract | Four chelate complexes, [Co(CNC
6
H
3
iPr
2
-2,6)
3
P(C
6
H
4
Me-p)
2
CH
2
CH
2
P(C
6
H
4
Me-p)
2
]BF
4
, [Co(CNC
6
H
3
iPr
2
-2,6)
3
PPh
2
CH=CHPPh
2
-cis]BF
4
, [Co(CNC
6
H
3
iPr
2
-2,6)
3
PPh
2
C
6
H
4
PPh
2
-o]BF
4
, and [Co(CNC
6
H
3
iPr
2
-2,6)
3
P(C
6
H
4
CF
3
-p)
2
CH
2
CH
2
P(C
6
H
4
CF
3
-p)
2
]BF
4
, have been synthesized by substitution reactions of [Co(CNC
6
H
3
iPr
2
-2,6)
5
]BF
4
at elevated temperatures and/or prolonged reaction times. The complexes have been characterized by IR and electronic spectra,
31
P NMR, cyclic voltammetry, and mass spectrometry. Comparisons are made with the pentakis(arylisocyanide)cobalt(I) complexes mono-substituted with diphosphine ligands. |
|---|---|
| AbstractList | Four chelate complexes, [Co(CNC
6
H
3
iPr
2
-2,6)
3
P(C
6
H
4
Me-p)
2
CH
2
CH
2
P(C
6
H
4
Me-p)
2
]BF
4
, [Co(CNC
6
H
3
iPr
2
-2,6)
3
PPh
2
CH=CHPPh
2
-cis]BF
4
, [Co(CNC
6
H
3
iPr
2
-2,6)
3
PPh
2
C
6
H
4
PPh
2
-o]BF
4
, and [Co(CNC
6
H
3
iPr
2
-2,6)
3
P(C
6
H
4
CF
3
-p)
2
CH
2
CH
2
P(C
6
H
4
CF
3
-p)
2
]BF
4
, have been synthesized by substitution reactions of [Co(CNC
6
H
3
iPr
2
-2,6)
5
]BF
4
at elevated temperatures and/or prolonged reaction times. The complexes have been characterized by IR and electronic spectra,
31
P NMR, cyclic voltammetry, and mass spectrometry. Comparisons are made with the pentakis(arylisocyanide)cobalt(I) complexes mono-substituted with diphosphine ligands. |
| Author | Becker, C. A. L. Mbaiwa, F. Foster |
| Author_xml | – sequence: 1 givenname: F. Foster surname: Mbaiwa fullname: Mbaiwa, F. Foster organization: Department of Chemistry , University of Botswana – sequence: 2 givenname: C. A. L. surname: Becker fullname: Becker, C. A. L. email: Beckerca@mopipi.ub.bw organization: Department of Chemistry , University of Botswana |
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| Cites_doi | 10.1039/a807799a 10.1039/dt9730001747 10.1021/cr00043a002 10.1021/ic50115a025 10.1351/pac199971081443 10.1016/j.ica.2004.03.035 10.1139/v03-100 10.1039/b212096h 10.1080/00958979308037127 10.1080/00958979308022757 10.1021/ac60210a007 10.1021/ic50144a032 10.1021/ed060p697 10.1016/S0020-1693(00)84665-4 10.1021/ed060p772 10.1016/j.ica.2005.11.006 |
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| Copyright | Copyright Taylor & Francis Group, LLC 2007 |
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| Snippet | Four chelate complexes, [Co(CNC
6
H
3
iPr
2
-2,6)
3
P(C
6
H
4
Me-p)
2
CH
2
CH
2
P(C
6
H
4
Me-p)
2
]BF
4
, [Co(CNC
6
H
3
iPr
2
-2,6)
3
PPh
2
CH=CHPPh
2
-cis]BF... |
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| StartPage | 153 |
| SubjectTerms | Arylisocyanide Cobalt(I) complex Cyclic voltammetry Diphosphine P-NMR |
| Title | Chelate complexes from diphosphine substitution in pentakis(arylisocyanide)cobalt(I) complexes |
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