PREPARATION OF BETA-TRIFLUOROMETHYL-GAMMA-BUTYROLACTONES VIA CLAISEN REARRANGEMENT

The Claisen rearrangement of allylic alcohol 2 provided the beta-trifluoromethyl gamma,delta-ethylenic ester 3 which gave access to a series of beta-trifluoromethyl-gamma-butyrolactones 1.

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Bibliographic Details
Published inSynthesis (Stuttgart) no. 2; pp. 167 - 169
Main Authors HADDAD, M, MOLINES, H, WAKSELMAN, C
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 1994
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
ACID
CONVERSION
BUILDING-BLOCKS
OZONOLYSIS
LACTONIZATION
CLAISEN REARRANGEMENT
TRICHLOROMETHYLATED ALLYLIC ALCOHOLS
DERIVATIVES
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Summary:The Claisen rearrangement of allylic alcohol 2 provided the beta-trifluoromethyl gamma,delta-ethylenic ester 3 which gave access to a series of beta-trifluoromethyl-gamma-butyrolactones 1.
ISSN:0039-7881
DOI:10.1055/s-1994-25430