Thermogravimetric analysis of co-combustion between municipal sewage sludge and coal slime: Combustion characteristics, interaction and kinetics

• Published in: Thermochimica acta Vol. 706; p. 179056
• Main Authors: Wang, Yanlin, Jia, Li, Guo, Jinrong, Wang, Biru, Zhang, Liu, Xiang, Jun, Jin, Yan
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.12.2021
• Subjects: Co-combustion characteristics; Coal slime; Interaction; Kinetics; Municipal sewage sludge; Municipal sewage sludge; Co-combustion characteristics; Kinetics; Coal slime; Interaction
• ISSN: 0040-6031; 1872-762X
• DOI: 10.1016/j.tca.2021.179056

•The co-combustion characteristics of sewage sludge (SS) and coal slime (CS) were investigated by thermogravimetric analyzer.•The interaction between SS and CS improved the ignition performance and burnout performance of the blends.•A synergy index was proposed to quantify the degree of synergy.•The reaction rate equations of SS-CS were obtain based on FWO and KAS methods combined with the master curve method. Based on the physical and chemical properties of municipal sewage sludge (SS) and coal slime (CS), the combustion behaviors of SS, CS and their blends were investigated by the thermogravimetric analyzer. The interaction between SS and CS was evaluated, and the combustion reaction rate equations were obtained. The results suggest that during the co-combustion, SS could improve the ignition performance, while CS could enhance the activity in the high temperature zone and improve the slagging characteristics. There was the most significant interaction in 550–600℃, which had a positive effect on the entire combustion process, and the synergy reached its peak when the CS ratio was 40% with synergy index SI=1.53. The combustion of the blend was a multi-step process, which conformed to the nth-order model, and the addition of CS could reduce the apparent activation energy of SS during the entire combustion process. [Display omitted]