Tailoring the transport and magnetic properties of Mn doped spinel FeCo2O4 and their impact on energy storage properties: A new strategy to improve storage performance

• Published in: Journal of energy storage Vol. 44; p. 103361
• Main Authors: Singh, Milan, Dubey, Brahma Prakash, Sahoo, Asit, Yadav, K L, Sharma, Yogesh
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.12.2021
• Subjects: Doping; FeCo2O4; Magnetic; Supercapacitor; Transport; Supercapacitor; Magnetic; Transport; FeCo2O4; Doping
• ISSN: 2352-152X; 2352-1538
• DOI: 10.1016/j.est.2021.103361

•The effect of doping (Mn) on the structure, morphology and transport properties of cobaltite is studied.•Mn incorporation into the FeCo2O4 enhances the saturation magnetization (MS) value.•Effect of external magnetic field on transport and supercapacitive properties is studied.•Relation between magnetic, electric and storage properties is established. Spinel FeMnxCo2-xO4 (x = 0, 0.1, 0.2 and 0.4) nanofibers were successfully synthesized by electrospinning technique. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and FESEM, techniques were used to characterize phase, oxidation states, and morphology of synthesized materials. Magnetic properties of materials were inverstigated using vibrating sample magnetometer (VSM). At room temperature, ferromagnetic character was shown by all the samples and maximum saturated magnetization (32 emu g−1) obtained for x = 0.4 sample. To study the electrical transport with and without magnetic field. A detailed transport analysis of FeMnxCo2-xO4 (x = 0, 0.1, 0.2 and 0.4) nanofibers are carried out where highest conductivity (2.08×10−5 S cm−1) was obtained for x = 0.2. This may be because of higher interfacial area or grain boundaries that may acting as short-circuiting pathways for easy ionic movement. However, under magnetic environment, conductivity of x = 0.4 samples is increased by almost two times, justifying the importance of this material in magnetoelectric applications. Furthermore, magnetic field driven supercapacitive storage analysis was also performed under small magnetic field of 3 mT. A huge increment in capacitance value form 191 F g−1 to 308 F g−1 is observed for x = 0.4 sample. Magnetic and electrical properties of Mn-doped FeCo2O4 have been found crucial to alter the supercapacitive properties. This study is unraveling a new tactic for improving the energy storage properties of a given material. [Display omitted]