Synthesis of thiophosphates by visible-light Daual photoredox/nickel catalysis

A visible-light-promoted photoredox/nickel protocol for Synthesis of thiophosphates with trimethylsilyl thioether and P(O)H compounds is described. In this transformation, S–P(O) bond formation are particularly attractive since they provide a straightforward, nontoxic, and high efficiency protocol f...

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Bibliographic Details
Published inTetrahedron Vol. 136; pp. 133338 - 133344
Main Authors Liu, Hongqiang, Zhu, Sihan, Zhao, Min, Li, Wenjing, Xu, Xia, Zhuang, Yuguo, Han, Deman
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 25.04.2023
Elsevier
Subjects
Chemistry
Chemistry, Organic
Diphenylphosphine oxide
Nickel catalysis
Physical Sciences
Science & Technology
Thiophosphonate
Trimethylsilyl thioether
Diphenylphosphine oxide
Trimethylsilyl thioether
Nickel catalysis
Thiophosphonate
ALCOHOLS
THIOLS
PHOSPHONATES
GENERATION
RADICALS
SECONDARY PHOSPHINE OXIDES
DERIVATIVES
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Summary:A visible-light-promoted photoredox/nickel protocol for Synthesis of thiophosphates with trimethylsilyl thioether and P(O)H compounds is described. In this transformation, S–P(O) bond formation are particularly attractive since they provide a straightforward, nontoxic, and high efficiency protocol for thiophosphates formation under pleasant smell during the experimental process. This strategy shows a new approach to conduct and can be scaled-up, and various sulfur-containing organophosphorus are readily obtained in moderate to excellent yields with excellent chemoselectivity and good functional-group tolerance. To create your abstract, type over the instructions in the template box below.Fonts or abstract dimensions should not be changed or altered. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2023.133338