Simultaneous spectrophotometric determination of ceftazidime and sulbactam using multivariate calibration methods
The simultaneous spectrophotometric determination of ceftazidime (CTZ) and sulbactam (SBT) in the presence of the overlapping spectra were accomplished with the partial least squares (PLS) and genetic algorithm-partial least squares (GA-PLS) approaches. In this study, the calibration set was based o...
Saved in:
| Published in | RSC advances Vol. 4; no. 77; pp. 41039 - 41044 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
01.01.2014
|
| Subjects | |
| Online Access | Get full text |
| ISSN | 2046-2069 2046-2069 |
| DOI | 10.1039/C4RA05562D |
Cover
| Abstract | The simultaneous spectrophotometric determination of ceftazidime (CTZ) and sulbactam (SBT) in the presence of the overlapping spectra were accomplished with the partial least squares (PLS) and genetic algorithm-partial least squares (GA-PLS) approaches. In this study, the calibration set was based on the absorption spectra in the range of 230–350 nm for 25 different mixtures of CTZ and SBT. The calibration curve was linear over the concentration range of 2–30 and 4–46 μg mL
−1
for CTZ and SBT, respectively. These two methods were tested by analyzing the synthetic mixtures of the CTZ and SBT and they were applied to real samples containing a commercial pharmaceutical preparation of the subject drugs. Good results were obtained by the two methods. However, the accuracy of the GA-PLS method was better than that of the PLS method. |
|---|---|
| AbstractList | The simultaneous spectrophotometric determination of ceftazidime (CTZ) and sulbactam (SBT) in the presence of the overlapping spectra were accomplished with the partial least squares (PLS) and genetic algorithm-partial least squares (GA-PLS) approaches. In this study, the calibration set was based on the absorption spectra in the range of 230-350 nm for 25 different mixtures of CTZ and SBT. The calibration curve was linear over the concentration range of 2-30 and 4-46 mu g mL super(-1) for CTZ and SBT, respectively. These two methods were tested by analyzing the synthetic mixtures of the CTZ and SBT and they were applied to real samples containing a commercial pharmaceutical preparation of the subject drugs. Good results were obtained by the two methods. However, the accuracy of the GA-PLS method was better than that of the PLS method. The simultaneous spectrophotometric determination of ceftazidime (CTZ) and sulbactam (SBT) in the presence of the overlapping spectra were accomplished with the partial least squares (PLS) and genetic algorithm-partial least squares (GA-PLS) approaches. In this study, the calibration set was based on the absorption spectra in the range of 230–350 nm for 25 different mixtures of CTZ and SBT. The calibration curve was linear over the concentration range of 2–30 and 4–46 μg mL −1 for CTZ and SBT, respectively. These two methods were tested by analyzing the synthetic mixtures of the CTZ and SBT and they were applied to real samples containing a commercial pharmaceutical preparation of the subject drugs. Good results were obtained by the two methods. However, the accuracy of the GA-PLS method was better than that of the PLS method. The simultaneous spectrophotometric determination of ceftazidime (CTZ) and sulbactam (SBT) in the presence of the overlapping spectra were accomplished with the partial least squares (PLS) and genetic algorithm-partial least squares (GA-PLS) approaches. In this study, the calibration set was based on the absorption spectra in the range of 230–350 nm for 25 different mixtures of CTZ and SBT. The calibration curve was linear over the concentration range of 2–30 and 4–46 μg mL⁻¹ for CTZ and SBT, respectively. These two methods were tested by analyzing the synthetic mixtures of the CTZ and SBT and they were applied to real samples containing a commercial pharmaceutical preparation of the subject drugs. Good results were obtained by the two methods. However, the accuracy of the GA-PLS method was better than that of the PLS method. |
| Author | Ganjali, Mohammad Reza Banaei, Alireza Pourbasheer, Eslam Norouzi, Parviz Mahramyari, Shiva |
| Author_xml | – sequence: 1 givenname: Shiva surname: Mahramyari fullname: Mahramyari, Shiva organization: Department of Chemistry, Payame Noor University (PNU), Tehran, Iran – sequence: 2 givenname: Eslam surname: Pourbasheer fullname: Pourbasheer, Eslam organization: Department of Chemistry, Payame Noor University (PNU), Tehran, Iran – sequence: 3 givenname: Alireza surname: Banaei fullname: Banaei, Alireza organization: Department of Chemistry, Payame Noor University (PNU), Tehran, Iran – sequence: 4 givenname: Mohammad Reza surname: Ganjali fullname: Ganjali, Mohammad Reza organization: Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran, Iran, Biosensor Research Center – sequence: 5 givenname: Parviz surname: Norouzi fullname: Norouzi, Parviz organization: Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran, Iran, Biosensor Research Center |
| BookMark | eNqFkUtLxDAUhYOM4DjOxl-QpQjVm_SRdjmMTxgQfKxLmt44kbaZSVJBf70dKygieDfnLr5zuI9DMulsh4QcMzhjEBfny-R-AWma8Ys9MuWQZBGHrJj86A_I3PsXGCpLGc_YlGwfTNs3QXZoe0_9BlVwdrO2wbYYnFG0xoCuNZ0MxnbUaqpQB_luatMilV1Nfd9UUgXZ0t6b7pnu4syrdEYGpEo2pnKjdwhc29ofkX0tG4_zL52Rp6vLx-VNtLq7vl0uVpHihQhRlQ6aSJ1rhDyHFHTGBNdc50LFgEUlRM45oGaaizitIeGZSBRLKoSMxVU8Iydj7sbZbY8-lK3xCptm3LXkMUu5SEQC_6JMxDBMIBgb0NMRVc5671CXG2da6d5KBuXuC-X3FwYYfsHKhM9jBCdN85flAzbxjS4 |
| CitedBy_id | crossref_primary_10_1007_s13738_017_1111_3 crossref_primary_10_1134_S1061934820090129 crossref_primary_10_1016_j_talanta_2020_121168 crossref_primary_10_1007_s11696_022_02494_5 crossref_primary_10_1002_jssc_201600639 crossref_primary_10_1002_slct_202305023 crossref_primary_10_1016_j_snb_2016_03_061 crossref_primary_10_1039_C5RA11751H crossref_primary_10_1002_pssa_202400654 crossref_primary_10_1016_j_chemolab_2015_08_011 crossref_primary_10_1149_1945_7111_ac53ce crossref_primary_10_1002_jssc_201601453 crossref_primary_10_1016_j_chroma_2018_03_042 crossref_primary_10_1590_fst_07020 crossref_primary_10_1186_s13065_023_01028_8 crossref_primary_10_1021_acsomega_4c01225 crossref_primary_10_1039_C6AY00309E crossref_primary_10_1016_j_chemolab_2016_03_022 |
| Cites_doi | 10.2478/v10007-008-0017-0 10.1002/jccs.200800025 10.1016/S0731-7085(02)00029-8 10.3844/ajassp.2009.1781.1787 10.1016/j.ijantimicag.2006.02.017 10.1080/00032710802240818 10.1016/S0039-9140(98)00271-9 10.1039/a900856j 10.1016/S0731-7085(96)01963-2 10.2174/157341208786306243 10.1016/j.aca.2005.08.017 10.1016/j.ijantimicag.2005.12.014 10.1002/adic.200790008 10.1016/j.tvjl.2007.06.026 10.1007/s00706-009-0155-1 10.1093/jac/8.suppl_B.227 10.2165/00003495-199549040-00008 10.1021/ac00162a020 10.1016/S0731-7085(03)00429-1 10.1016/j.jchromb.2011.05.021 10.1016/S0169-7439(98)00051-3 10.1111/j.2517-6161.1974.tb00994.x 10.2174/157341207782418802 10.1016/S0378-4347(98)00333-8 10.1039/an9840901057 10.1016/j.ijantimicag.2003.10.008 10.1111/j.1750-3841.2009.01458.x 10.1016/j.jchromb.2010.09.021 10.3923/ijp.2010.271.277 10.1021/ac00209a024 10.1039/b003805i |
| ContentType | Journal Article |
| DBID | AAYXX CITATION 7SR 8BQ 8FD JG9 7S9 L.6 |
| DOI | 10.1039/C4RA05562D |
| DatabaseName | CrossRef Engineered Materials Abstracts METADEX Technology Research Database Materials Research Database AGRICOLA AGRICOLA - Academic |
| DatabaseTitle | CrossRef Materials Research Database Engineered Materials Abstracts Technology Research Database METADEX AGRICOLA AGRICOLA - Academic |
| DatabaseTitleList | Materials Research Database CrossRef AGRICOLA |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 2046-2069 |
| EndPage | 41044 |
| ExternalDocumentID | 10_1039_C4RA05562D |
| GroupedDBID | 0-7 0R~ 53G AAEMU AAFWJ AAHBH AAIWI AAJAE AARTK AAWGC AAXHV AAYXX ABASK ABEMK ABIQK ABJNI ABPDG ABXOH ACGFS ADBBV ADMRA AEFDR AENEX AESAV AETIL AFLYV AFPKN AFRZK AFVBQ AGEGJ AGRSR AHGCF AKBGW AKMSF ALMA_UNASSIGNED_HOLDINGS ANBJS ANUXI APEMP ASKNT AUDPV BCNDV BLAPV BSQNT C6K CITATION EBS ECGLT EE0 EF- EJD GROUPED_DOAJ H13 HZ~ H~N J3G J3H J3I M~E O9- OK1 PGMZT R7C R7G RAOCF RCNCU RPM RPMJG RRC RSCEA RVUXY SLH YAE ZCN 7SR 8BQ 8FD JG9 7S9 L.6 |
| ID | FETCH-LOGICAL-c297t-b5c294af8fe088050f6172f2f87c30e9b778220ef1f2735d042674c14be0613b3 |
| ISSN | 2046-2069 |
| IngestDate | Fri Jul 11 02:54:12 EDT 2025 Fri Jul 11 10:49:56 EDT 2025 Tue Jul 01 03:53:48 EDT 2025 Thu Apr 24 23:08:07 EDT 2025 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 77 |
| Language | English |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c297t-b5c294af8fe088050f6172f2f87c30e9b778220ef1f2735d042674c14be0613b3 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| PQID | 1730050711 |
| PQPubID | 23500 |
| PageCount | 6 |
| ParticipantIDs | proquest_miscellaneous_2315274740 proquest_miscellaneous_1730050711 crossref_primary_10_1039_C4RA05562D crossref_citationtrail_10_1039_C4RA05562D |
| ProviderPackageCode | CITATION AAYXX |
| PublicationCentury | 2000 |
| PublicationDate | 2014-01-01 |
| PublicationDateYYYYMMDD | 2014-01-01 |
| PublicationDate_xml | – month: 01 year: 2014 text: 2014-01-01 day: 01 |
| PublicationDecade | 2010 |
| PublicationTitle | RSC advances |
| PublicationYear | 2014 |
| References | Khajehsharifi (C4RA05562D-(cit18)/*[position()=1]) 2009; 140 Ayrton (C4RA05562D-(cit8)/*[position()=1]) 1981; 8 Beheshti (C4RA05562D-(cit27)/*[position()=1]) 2010; 75 Gonzalez (C4RA05562D-(cit30)/*[position()=1]) 1999; 48 Stone (C4RA05562D-(cit32)/*[position()=1]) 1974; 36 Ródenas (C4RA05562D-(cit7)/*[position()=1]) 1997; 15 Brereton (C4RA05562D-(cit20)/*[position()=1]) 2000; 125 Wang (C4RA05562D-(cit13)/*[position()=1]) 2004; 23 Haaland (C4RA05562D-(cit25)/*[position()=1]) 1988; 60 Moreno (C4RA05562D-(cit6)/*[position()=1]) 2008; 41 Khajehsharifi (C4RA05562D-(cit28)/*[position()=1]) 2008; 55 Pei (C4RA05562D-(cit12)/*[position()=1]) 2011; 879 Haaland (C4RA05562D-(cit26)/*[position()=1]) 1990; 62 Dailly (C4RA05562D-(cit2)/*[position()=1]) 2006; 27 Rains (C4RA05562D-(cit4)/*[position()=1]) 1995; 49 Zhou (C4RA05562D-(cit11)/*[position()=1]) 2010; 878 Pajchel (C4RA05562D-(cit15)/*[position()=1]) 2002; 29 Haginaka (C4RA05562D-(cit14)/*[position()=1]) 1984; 109 Riahi (C4RA05562D-(cit29)/*[position()=1]) 2007; 3 Hung (C4RA05562D-(cit10)/*[position()=1]) 2007; 29 Riahi (C4RA05562D-(cit22)/*[position()=1]) 2008; 4 Leardi (C4RA05562D-(cit31)/*[position()=1]) 1998; 41 Arancibia (C4RA05562D-(cit17)/*[position()=1]) 2005; 553 Kaur (C4RA05562D-(cit21)/*[position()=1]) 2007; 97 Albarellos (C4RA05562D-(cit1)/*[position()=1]) 2008; 178 Guitton (C4RA05562D-(cit9)/*[position()=1]) 1998; 719 Siddiqui (C4RA05562D-(cit16)/*[position()=1]) 2010; 6 Martens (C4RA05562D-(cit19)/*[position()=1]) 1989 Markopoulou (C4RA05562D-(cit24)/*[position()=1]) 2003; 33 Siddiqui (C4RA05562D-(cit3)/*[position()=1]) 2009; 6 Hiremath (C4RA05562D-(cit5)/*[position()=1]) 2008; 58 Blanco (C4RA05562D-(cit23)/*[position()=1]) 1999; 124 |
| References_xml | – volume: 58 start-page: 275 year: 2008 ident: C4RA05562D-(cit5)/*[position()=1] publication-title: Acta Pharm. doi: 10.2478/v10007-008-0017-0 – volume: 55 start-page: 163 year: 2008 ident: C4RA05562D-(cit28)/*[position()=1] publication-title: J. Chin. Chem. Soc. doi: 10.1002/jccs.200800025 – volume: 29 start-page: 75 year: 2002 ident: C4RA05562D-(cit15)/*[position()=1] publication-title: J. Pharm. Biomed. Anal. doi: 10.1016/S0731-7085(02)00029-8 – volume: 6 start-page: 1781 year: 2009 ident: C4RA05562D-(cit3)/*[position()=1] publication-title: Am. J. Appl. Sci. doi: 10.3844/ajassp.2009.1781.1787 – volume: 29 start-page: 145 year: 2007 ident: C4RA05562D-(cit10)/*[position()=1] publication-title: Int. J. Antimicrob. Agents doi: 10.1016/j.ijantimicag.2006.02.017 – volume: 41 start-page: 2143 year: 2008 ident: C4RA05562D-(cit6)/*[position()=1] publication-title: Anal. Lett. doi: 10.1080/00032710802240818 – volume: 48 start-page: 729 year: 1999 ident: C4RA05562D-(cit30)/*[position()=1] publication-title: Talanta doi: 10.1016/S0039-9140(98)00271-9 – volume: 124 start-page: 911 year: 1999 ident: C4RA05562D-(cit23)/*[position()=1] publication-title: Analyst doi: 10.1039/a900856j – volume: 15 start-page: 1687 year: 1997 ident: C4RA05562D-(cit7)/*[position()=1] publication-title: J. Pharm. Biomed. Anal. doi: 10.1016/S0731-7085(96)01963-2 – volume: 4 start-page: 231 year: 2008 ident: C4RA05562D-(cit22)/*[position()=1] publication-title: Curr. Pharm. Anal. doi: 10.2174/157341208786306243 – volume: 553 start-page: 141 year: 2005 ident: C4RA05562D-(cit17)/*[position()=1] publication-title: Anal. Chim. Acta doi: 10.1016/j.aca.2005.08.017 – volume: 27 start-page: 553 year: 2006 ident: C4RA05562D-(cit2)/*[position()=1] publication-title: Int. J. Antimicrob. Agents doi: 10.1016/j.ijantimicag.2005.12.014 – volume: 97 start-page: 237 year: 2007 ident: C4RA05562D-(cit21)/*[position()=1] publication-title: Ann. Chim. doi: 10.1002/adic.200790008 – volume: 178 start-page: 238 year: 2008 ident: C4RA05562D-(cit1)/*[position()=1] publication-title: Vet. J. doi: 10.1016/j.tvjl.2007.06.026 – volume: 140 start-page: 685 year: 2009 ident: C4RA05562D-(cit18)/*[position()=1] publication-title: Monatshefte für Chemie - Chemical Monthly doi: 10.1007/s00706-009-0155-1 – volume: 8 start-page: 227 year: 1981 ident: C4RA05562D-(cit8)/*[position()=1] publication-title: J. Antimicrob. Chemother. doi: 10.1093/jac/8.suppl_B.227 – volume-title: Multivariate Calibration year: 1989 ident: C4RA05562D-(cit19)/*[position()=1] – volume: 49 start-page: 577 year: 1995 ident: C4RA05562D-(cit4)/*[position()=1] publication-title: Drugs doi: 10.2165/00003495-199549040-00008 – volume: 60 start-page: 1193 year: 1988 ident: C4RA05562D-(cit25)/*[position()=1] publication-title: Anal. Chem. doi: 10.1021/ac00162a020 – volume: 33 start-page: 1163 year: 2003 ident: C4RA05562D-(cit24)/*[position()=1] publication-title: J. Pharm. Biomed. Anal. doi: 10.1016/S0731-7085(03)00429-1 – volume: 879 start-page: 2000 year: 2011 ident: C4RA05562D-(cit12)/*[position()=1] publication-title: J. Chromatogr. B: Biomed. Sci. Appl. doi: 10.1016/j.jchromb.2011.05.021 – volume: 41 start-page: 195 year: 1998 ident: C4RA05562D-(cit31)/*[position()=1] publication-title: Chemom. Intell. Lab. Syst. doi: 10.1016/S0169-7439(98)00051-3 – volume: 36 start-page: 111 year: 1974 ident: C4RA05562D-(cit32)/*[position()=1] publication-title: J. Roy. Stat. Soc. B Stat. Meth. doi: 10.1111/j.2517-6161.1974.tb00994.x – volume: 3 start-page: 268 year: 2007 ident: C4RA05562D-(cit29)/*[position()=1] publication-title: Curr. Pharm. Anal. doi: 10.2174/157341207782418802 – volume: 719 start-page: 151 year: 1998 ident: C4RA05562D-(cit9)/*[position()=1] publication-title: J. Chromatogr. B: Biomed. Sci. Appl. doi: 10.1016/S0378-4347(98)00333-8 – volume: 109 start-page: 1057 year: 1984 ident: C4RA05562D-(cit14)/*[position()=1] publication-title: Analyst doi: 10.1039/an9840901057 – volume: 23 start-page: 590 year: 2004 ident: C4RA05562D-(cit13)/*[position()=1] publication-title: Int. J. Antimicrob. Agents doi: 10.1016/j.ijantimicag.2003.10.008 – volume: 75 start-page: C135 year: 2010 ident: C4RA05562D-(cit27)/*[position()=1] publication-title: J. Food Sci. doi: 10.1111/j.1750-3841.2009.01458.x – volume: 878 start-page: 3119 year: 2010 ident: C4RA05562D-(cit11)/*[position()=1] publication-title: J. Chromatogr. B: Biomed. Sci. Appl. doi: 10.1016/j.jchromb.2010.09.021 – volume: 6 start-page: 271 year: 2010 ident: C4RA05562D-(cit16)/*[position()=1] publication-title: Int. J. Pharmacol. doi: 10.3923/ijp.2010.271.277 – volume: 62 start-page: 1091 year: 1990 ident: C4RA05562D-(cit26)/*[position()=1] publication-title: Anal. Chem. doi: 10.1021/ac00209a024 – volume: 125 start-page: 2125 year: 2000 ident: C4RA05562D-(cit20)/*[position()=1] publication-title: Analyst doi: 10.1039/b003805i |
| SSID | ssj0000651261 |
| Score | 2.174651 |
| Snippet | The simultaneous spectrophotometric determination of ceftazidime (CTZ) and sulbactam (SBT) in the presence of the overlapping spectra were accomplished with... |
| SourceID | proquest crossref |
| SourceType | Aggregation Database Enrichment Source Index Database |
| StartPage | 41039 |
| SubjectTerms | Absorption spectra Algorithms Calibration ceftazidime Drugs Genetics least squares Least squares method Spectra spectral analysis Spectrophotometry sulbactam |
| Title | Simultaneous spectrophotometric determination of ceftazidime and sulbactam using multivariate calibration methods |
| URI | https://www.proquest.com/docview/1730050711 https://www.proquest.com/docview/2315274740 |
| Volume | 4 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Lb9swDBa27rBdhj2x7gUN22UIvPkhx_WxyPrA0HRAkwC5GZQswSlqu0udAs2hv72U5FfQFuh2cWJHFhDxA_lRJEVCvqUc7bgA7igkDw5L0U-JwfOdoWSpbnk1FKBrh8fHw8MZ-z0P510oxlSXVPyHWN9ZV_I_UsVnKFddJfsPkm0nxQf4HeWLV5QwXh8k48lC5wNCIXUeq6mZXJbnWVmVue6TJQZpk-vS0EIhVQXrRbrIbdTgYnXGQVSQD1Zmz8CkF16i-4wMdIDS0760edc2mr7oU9mTyajJIGh5-RiyJeRXYMvXJxnO1epe_ENoMjNZF9hoKHbbqAXIha23QRW8bl86gOIUbAH3uMwgz0FXU9a_13sVHuvtVUij03x0x1GEtjtLo4BZD2d1TxerTZmOU_dMM97bwyJv6X0ch8ISbAn6cCA_7axbE9E__pPsz46OkunefPqYPPGjyET1x9fdlhyyMQ8dyuYQ2yD-2U24SVs2rbahItMX5HntQ9BdC4iX5JEsXpGno6Z132vytw8MehsYdAMYtFS0BwyKwKAtMKgBBu0Dg_aAQWtgvCGz_b3p6NCpe2s4wo-jyuEhfjJQO0qinXFDV2kqq3y1E4nAlTGPNHV0pfIUEtww1a52xITHuNQMkAdvyVZRFvIdoeDFIEUAEUhgbsR5gJR1GIOveKTp-Tb53ixdIuqD53X_k7PEJEAEcTJiJ7tmmX9tk6_t2HN73Mqdo740EkhwZXWIy65o4pn2C0ibvfvHoFIK9V4Mc98_YJ4P5FmH5I9kq1qu5CfkoRX_bNBzA9MAlHM |
| linkProvider | ISSN International Centre |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Simultaneous+spectrophotometric+determination+of+ceftazidime+and+sulbactam+using+multivariate+calibration+methods&rft.jtitle=RSC+advances&rft.au=Mahramyari%2C+Shiva&rft.au=Pourbasheer%2C+Eslam&rft.au=Banaei%2C+Alireza&rft.au=Ganjali%2C+Mohammad+Reza&rft.date=2014-01-01&rft.eissn=2046-2069&rft.volume=4&rft.issue=77&rft.spage=41039&rft.epage=41044&rft_id=info:doi/10.1039%2Fc4ra05562d&rft.externalDBID=NO_FULL_TEXT |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2046-2069&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2046-2069&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2046-2069&client=summon |