Ruthenium-catalyzed aerobic oxidative coupling of alkynes with 2-aryl-substituted pyrroles
Ruthenium-catalyzed aerobic oxidative annulations of alkynes were accomplished with co-catalytic amounts of Cu(OAc)2[middle dot]H2O under ambient air. The C-H/N-H bond functionalization occurred with unparalleled selectivities and ample scope to deliver structural analogs of bioactive marine alkaloi...
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| Published in | Chemical science (Cambridge) Vol. 3; no. 1; pp. 177 - 180 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
01.01.2012
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Ruthenium-catalyzed aerobic oxidative annulations of alkynes were accomplished with co-catalytic amounts of Cu(OAc)2[middle dot]H2O under ambient air. The C-H/N-H bond functionalization occurred with unparalleled selectivities and ample scope to deliver structural analogs of bioactive marine alkaloids. |
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| AbstractList | Ruthenium-catalyzed aerobic oxidative annulations of alkynes were accomplished with co-catalytic amounts of Cu(OAc)2[middle dot]H2O under ambient air. The C-H/N-H bond functionalization occurred with unparalleled selectivities and ample scope to deliver structural analogs of bioactive marine alkaloids. |
| Author | Wang, Lianhui Lygin, Alexander V Ackermann, Lutz |
| Author_xml | – sequence: 1 givenname: Lutz surname: Ackermann fullname: Ackermann, Lutz – sequence: 2 givenname: Lianhui surname: Wang fullname: Wang, Lianhui – sequence: 3 givenname: Alexander surname: Lygin middlename: V fullname: Lygin, Alexander V |
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| Snippet | Ruthenium-catalyzed aerobic oxidative annulations of alkynes were accomplished with co-catalytic amounts of Cu(OAc)2[middle dot]H2O under ambient air. The... |
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| SubjectTerms | Alkaloids Alkynes Analogs Bonding Joining Marine Pyrroles Selectivity |
| Title | Ruthenium-catalyzed aerobic oxidative coupling of alkynes with 2-aryl-substituted pyrroles |
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