Palladium-catalyzed carbene insertion into benzyl bromides

Palladium can catalyze the insertion of ethyl diazoacetate into benzyl bromides. The key step in the catalytic cycle is the migratory insertion of a carbene, derived from ethyl diazoacetate, into a Pd–C bond. Graphical Abstract

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Bibliographic Details
Published inTetrahedron Vol. 61; no. 26; pp. 6438 - 6441
Main Authors Greenman, Kevin L., Van Vranken, David L.
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 27.06.2005
Elsevier
Subjects
Carbene
Chemistry
Chemistry, Organic
Palladium
Physical Sciences
Science & Technology
Stoichiometric insertion
Stoichiometric insertion
Carbene
Palladium
N-HETEROCYCLIC CARBENE
stoichiometric insertion
CARBON
MIGRATORY INSERTION
COMPLEXES
HYDROLYSIS
palladium
ELIMINATION
carbene
DERIVATIVES
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Summary:Palladium can catalyze the insertion of ethyl diazoacetate into benzyl bromides. The key step in the catalytic cycle is the migratory insertion of a carbene, derived from ethyl diazoacetate, into a Pd–C bond. Graphical Abstract
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2005.03.108