Integration of microbial fuel cell and catalytic oxidation reactor with iron phthalocyanine catalyst for Congo red degradation

• Published in: Biochemical engineering journal Vol. 120; pp. 118 - 124
• Main Authors: Yuan, Guang-En, Li, Yunbei, Lv, Jinghua, Zhang, Guoquan, Yang, Fenglin
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.04.2017
• Subjects: Catalytic oxidation; Decolorization; Iron phthalocyanine; LC–MS analysis; Microbial fuel cell; Microbial fuel cell; Catalytic oxidation; Decolorization; Iron phthalocyanine; LC–MS analysis
• ISSN: 1369-703X; 1873-295X
• DOI: 10.1016/j.bej.2017.01.005

[Display omitted] •A MFC and a COR reactor were integrated together.•H2O2 and O2 can both be used as oxidants.•Over 90% of Congo red was degraded within 72h.•Stabilities of catalysts were evaluated after 100days of operation.•Congo red was degraded into less toxic and more biodegradable organics. An integrated system of a microbial fuel cell (MFC) and a catalytic oxidation reactor (COR) was developed. In the MFC-COR system, H2O2 generated at the MFC cathode and residual dissolved oxygen could both be used as oxidants for Congo red degradation in the presence of iron phthalocyanine-based catalyst. Over 90% of Congo red was degraded within 72h in neutral solution. The open-circuit potential and maximum power density of the MFC reactor were measured as 0.615V and 808.3mW/m3, respectively. The iron phthalocyanine-based catalyst was still active enough even after 33 cycles of operation. LC–MS analysis showed that Congo red was decomposed into less toxic and more biodegradable organics including malonic acid and maleic acid. This MFC-COR system can be a promising alternative for simultaneously biodegradable and refractory pollutant removal.