Structural phase transition from 1H to 1T′ at low pressure in supported monolayer WS2: Raman study

• Published in: Solid state communications Vol. 336; p. 114412
• Main Authors: Thomas, Anoop, Vikram, Kunwar, Muthu, D.V.S., Sood, A.K.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.10.2021
• Subjects: High pressure; Phase transition; Raman spectroscopy; Tungsten disulfide; Raman spectroscopy; Tungsten disulfide; Phase transition; High pressure
• ISSN: 0038-1098; 1879-2766
• DOI: 10.1016/j.ssc.2021.114412

We present pressure-dependent Raman studies on monolayer 1H tungsten disulfide (WS2) supported on a polymer substrate up to 20 GPa. The structural deformation starts at ~2.9 GPa by observing a split in A′1 mode. At ~8 GPa, first order Raman modes exhibit a change in pressure coefficients of phonon frequencies, and four new modes at 187, 248, 282, and 317 cm−1 appear, which become increasingly dominant with pressure. As the new modes are identified with the 1T′ phase, our Raman results show a mixed phase of 1T′ and 1H above 8 GPa. Our results suggest that biaxial (planar isotropic) compressive strain plays in inducing the phase ‬‬‬ transition at a relatively lower pressure in polymer-supported monolayer as compared to bulk WS2.‬ ‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬‬