Adsorption enhances CH4 transport-driven hydrate formation in size-varied ZIF-8: Micro-mechanism for CH4 storage by adsorption-hydration hybrid technology

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 482; p. 148957
• Main Authors: Chen, Shujun, Duan, Jun, Xie, Xianfeng, Fu, Yue, Zi, Mucong
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.02.2024
• Subjects: Adsorption-hydration hybrid; CH4 storage; Metal-organic framework; MRI; Particle size; Particle size; Metal-organic framework; MRI; CH4 storage; Adsorption-hydration hybrid
• ISSN: 1385-8947; 1873-3212
• DOI: 10.1016/j.cej.2024.148957

•Different ZIF-8 particles show variations in pore space for CH4/H2O aggregation.•Physisorption promotes CH4 transportation and hydrate formation in pore spaces.•Larger ZIF-8 particles enhance adsorption kinetics to rapid hydrate formation.•Two-way migration of CH4/H2O to promote hydrate growth in small pores. The adsorption-hydration hybrid technology holds significant potential for future CH4 storage applications. However, the transport of CH4/H2O and the mechanisms governing hydrate formation within metal-organic framework (MOF) systems remain unclear. In this study, the mechanism of CH4 adsorption, transport, and hydrate formation within ZIF-8 pores of different sizes was delineated utilizing the magnetic resonance imaging (MRI) technique. Primarily, CH4 undergoes physisorption within the inner cavity of ZIF-8, facilitating diffusion through the pores, which preferentially accumulate in larger pore spaces. Due to favorable interactions between CH4 and pre-absorbed water on the ZIF-8 surface, ZIF-8–01 and ZIF-8–02 preferentially facilitate substantial hydrate formation within larger pore spaces. The continuous hydrate growth depletes CH4 in the pore space, enabling two-way migration of adsorbed CH4 to support ongoing hydrate formation. This limited availability of adsorption sites within ZIF-8 induces the diffusion of surrounding CH4 into smaller pore spaces, facilitating the conversion of bound water. The size of the particles considerably influences the transport of physically adsorbed CH4 and impacts hydrate formation. Similar patterns are observed in the adsorption mass transfer coefficients of ZIF-8–01 and ZIF-8–02, which range from 0.0038 to 0.0044 and 0.0031 to 0.0124, respectively. The presence of more adsorption vacancies in the early stage leads to rapid diffusion adsorption of CH4 owing to strong adsorption effects. As adsorption within ZIF-8 pore cavities approaches saturation, increased water transport elevates internal gas-liquid two-phase resistance, slowing the kinetics of late-stage CH4 adsorption. At 6 MPa, CH4 with a larger particle size preferentially overcomes the gas-liquid energy barrier, expediting transport and promoting hydrate formation. Furthermore, the optimal particle sizes of ZIF-8 substantially influence physisorption and significantly improve the kinetics of hydrate formation.