Advances in the photoredox catalysis of S(VI) compounds

The S(VI) compounds, mainly sulfonamide functional groups are widely used in medicinal and agro-chemistry for almost a century. Other molecules with S(VI) centre, namely sulfones, sulfoximines, sulfonimidamides, sulfonimidates are presently receiving tremendous interest in several areas including me...

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Bibliographic Details
Published inTetrahedron Vol. 111; p. 132711
Main Authors Padma Priya, V.R., Natarajan, K., Nandi, Ganesh Chandra
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 09.04.2022
Subjects
Photoredox catalysis
Sulfonamides
Sulfonimidamides
Sulfonimidines
Sulfoximines
Photoredox catalysis
Sulfonimidines
Sulfonamides
Sulfoximines
Sulfonimidamides
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Summary:The S(VI) compounds, mainly sulfonamide functional groups are widely used in medicinal and agro-chemistry for almost a century. Other molecules with S(VI) centre, namely sulfones, sulfoximines, sulfonimidamides, sulfonimidates are presently receiving tremendous interest in several areas including medicinal and synthetic organic chemistry. Despite numerous methods following the traditional pathways have been developed to synthesize these molecules and their further organic transformations, currently, light driven photoredox catalytic techniques have occupied front row due to their close connections with green and sustainable chemistry. This review discusses the preparations and synthetic applications of S(VI) centre bearing molecules via photoredox catalysis in detail to date. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2022.132711