Syntheses and structural properties of severely distorted porphyrins: N-methyl derivatives

Syntheses and characterization of a series of N-methylated derivatives of sterically distorted porphyrins are reported; the work includes the first example of a tetra-N-methylated porphyrin obtained by methylation of an intact porphyrin.

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Bibliographic Details
Published inHeterocycles Vol. 45; no. 4; pp. 651 - 658
Main Authors Clement, TE, Nguyen, LT, Khoury, RG, Nurco, DJ, Smith, KM
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier 1997
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
NONPLANAR
MODELS
PHOTOSYNTHETIC CHROMOPHORES
LIGHT-ABSORPTION PROPERTIES
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Summary:Syntheses and characterization of a series of N-methylated derivatives of sterically distorted porphyrins are reported; the work includes the first example of a tetra-N-methylated porphyrin obtained by methylation of an intact porphyrin.
ISSN:0385-5414
DOI:10.3987/com-97-7754