Fluidic-chemical characteristics of electroless copper deposition of ordered mass-fabricated pillars in a microchannel for chip packaging applications

•Experimental results and observations are compared to an idealized simulation model.•Optimal deposition conditions for electroless plating in a microchannel are examined.•Low velocities are accompanied with hydrogen accumulations and extraneous deposition.•The deposition rate slows down for high el...

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Published inChemical engineering science Vol. 269; p. 118474
Main Authors Gräfner, Simon Johannes, Huang, Jeng-Hau, Renganathan, Vengudusamy, Kung, Po-Yu, Wu, Po-Yi, Kao, C.R.
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 05.04.2023
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Summary:•Experimental results and observations are compared to an idealized simulation model.•Optimal deposition conditions for electroless plating in a microchannel are examined.•Low velocities are accompanied with hydrogen accumulations and extraneous deposition.•The deposition rate slows down for high electrolyte velocities towards turbulent flow. The trend of chip-packaging in the semiconductor industry is pointing towards 3D integrated circuits and scaling down to attain devices with enhanced efficiency and performance. To overcome the reassimilating challenges, we propose the usage of an electroless plated deposition layer to connect pillar bumps and create high-density interconnections. The substrates and pillar arrangements encompass our microchannel with the height of 50 µm or 25 µm where in between the electrolyte is forced with a superficial velocity of 0.3 to 300 mm s−1 in our experiments. The results are compared to a numerical multi-physics model which simulates idealized plating conditions without any disruptions to characterize and quantify the different flow regimes and undesired side-effects. In the low-velocity regime, hydrogen bubbles cannot be dislodged and remain in the microchannel which is accompanied with the formation of extraneous deposition on the resist surface. The mid-velocity regime shows a good match to the simulation model and is considered as optimal plating condition. The chemical reaction slows down for high velocities.
ISSN:0009-2509
1873-4405
DOI:10.1016/j.ces.2023.118474