An approach to triquinane synthesis using the Pauson–Khand reaction

Tricyclic skeletons have been generated from acyclic enyne precursors by using an intramolecular Pauson–Khand reaction in combination with aldol, Michael and alkylation reactions. [Display omitted]

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Bibliographic Details
Published inTetrahedron Vol. 62; no. 50; pp. 11782 - 11792
Main Authors Krafft, Marie E., Kyne, Graham M., Hirosawa, Chitaru, Schmidt, Peter, Abboud, Khalil A., L'Helias, Nathalie
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 11.12.2006
Elsevier
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
ACCELERATION
CYCLIZATION APPROACH
CASCADE REACTIONS
VINYL SULFONES
STEREOSELECTIVITY
CONSTRUCTION
SESQUITERPENE
DERIVATIVES
ANGULAR TRIQUINANE
DIHYDROFURANS
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Summary:Tricyclic skeletons have been generated from acyclic enyne precursors by using an intramolecular Pauson–Khand reaction in combination with aldol, Michael and alkylation reactions. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2006.09.022