A latent curing agent for rapid curing of phenolic epoxy resin at low temperature

Developing effective latent curing agent for rapid curing of epoxy resins at low temperatures remains challenging. This study reports a latent curing agent, ortho‐cresol phenolic epoxy resin‐bisphenol A (EOCN‐BPA), prepared through the addition reaction of o‐methyl phenolic epoxy resin with BPA. Whe...

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Bibliographic Details
Published inJournal of applied polymer science Vol. 141; no. 39
Main Authors Guo, Jian‐Qiao, Zhang, Xing‐Hong
Format Journal Article
LanguageEnglish
Published Hoboken, USA John Wiley & Sons, Inc 15.10.2024
Wiley Subscription Services, Inc
Subjects
Bisphenol A
Catalysts
coatings
Curing
Curing agents
Epoxy phenol novolacs
Epoxy resins
Hydroxyl groups
Low temperature
Phenolic epoxy resins
Powder coating
Powder coatings
Reagents
resins
Room temperature
Softening points
Storage stability
Temperature
thermosets
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Summary:Developing effective latent curing agent for rapid curing of epoxy resins at low temperatures remains challenging. This study reports a latent curing agent, ortho‐cresol phenolic epoxy resin‐bisphenol A (EOCN‐BPA), prepared through the addition reaction of o‐methyl phenolic epoxy resin with BPA. When blended with dicyandiamide (DICY) in a 1:3 molar ratio, EOCN‐BPA/DICY is used to cure a linear epoxy phenolic novolac (EPN) resin (epoxy equivalent: 550 g eq−1, softening point: approximately 82°C), at an onset curing temperature of 90°C, which is considerably lower than the onset curing temperature of DICY with EPN (160°C). However, EOCN‐BPA does not react with EPN without a catalyst. Therefore, this latent curing system is successfully applied in powder coatings, rapid curing at 120°C within 3 min without an additional catalyst, outperforming the EPN/EOCN‐BPA system using cocatalyst 2‐methylimidazole. Consequently, DICY catalyzes the curing reaction between the phenol hydroxyl group and epoxy resin and participates in it. The prepared powder coating exhibits excellent storage stability, maintaining its properties for over 3 months at room temperature. These findings demonstrate the excellent latent properties of EOCN‐BPA/DICY, highlighting its potential as a highly effective latent curing agent. A Latent Curing Agent for Rapid Curing of Phenolic Epoxy Resin at Low Temperature.
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ISSN:0021-8995
1097-4628
DOI:10.1002/app.56003