Shish‐kebab structure evolution of HDPE/UHMWPE during hot drawing

• Published in: Polymer engineering and science Vol. 64; no. 6; pp. 2854 - 2867
• Main Authors: Zhang, Feng, Pan, Xuefeng, Li, Fengtao, Xu, Jiajia, He, Xuelian
• Format: Journal Article
• Language: English
• Published: Hoboken, USA John Wiley & Sons, Inc 01.06.2024; Blackwell Publishing Ltd
• Subjects: Composite materials; Crystal structure; Crystallization; Evolution; HDPE/UHMWPE; High density polyethylenes; Hot drawing; Lamellar structure; Mechanical properties; Mixtures; Molecular weight; Plastic deformation; Polyethylene; Reagents; shish‐kebab structure; Single crystals; small angle X‐ray scattering; solution blending; Strain; Stretching; Ultra high molecular weight polyethylene
• ISSN: 0032-3888; 1548-2634
• DOI: 10.1002/pen.26730

Using a solution‐mixing method, this research aimed to fabricate high‐density polyethylene (HDPE)/ultra‐high molecular weight polyethylene (UHMWPE) composite materials with uniform dispersion. By incorporating a small quantity of UHMWPE as a nucleating agent, additional contact points were introduced to enhance the crystallization rate of the HDPE matrix. Thermal stretching experiments were conducted on composite systems with varying UHMWPE contents and molecular weight additions at different temperatures. Elevating the stretching temperature was found to decrease the yield strain and yield strength, extend the stage of tensile plastic deformation, and diminish the overall mechanical properties of the composite material. Notably, stretching at temperatures ranging from 90 to 110°C accentuated the development of internal crystal orientation structures. Under low strain conditions, crystal slip was observed to be concentrated, with single crystals undergoing continuous stretching and breaking, resulting in a decrease in the long period. Conversely, at high strains, the induced formation of oriented lamellar structures was observed. Highlights Prepared HDPE/UHMWPE blends by UHMWPE with varying molecular weights. Analyzed the alterations in the HDPE/UHMWPE blends' internal crystal structure. Influence of UHMWPE addition, temperature on the evolution of crystal structure. Shishi‐kebab structures evolution.