Cu-doped ZnO/Ag/CuO heterostructure: superior photocatalysis and charge transfer

• Published in: RSC advances Vol. 14; no. 41; pp. 29763 - 29773
• Main Authors: Gebretsadik, Abbay, Kefale, Bontu, Sori, Chaluma, Tsegaye, Dereje, Ananda Murthy, H C, Abebe, Buzuayehu
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 18.09.2024; The Royal Society of Chemistry
• Subjects: Charge transfer; Chemistry; Copper; Copper oxides; Electromagnetic absorption; Electrons; Heterojunctions; Heterostructures; High resolution electron microscopy; Image resolution; Methylene blue; Photocatalysis; Polyvinyl alcohol; Silver; Surface plasmon resonance; Synthesis; X-ray diffraction; Zinc oxide; Zinc oxides
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/d4ra05989a

Doped semiconductor heterostructures have superior properties compared to their components. In this study, we observed the synthesis of Cu-doped ZnO/Ag/CuO heterostructure with the presence of charge transfer and visible light-harvesting properties resulting from doping and heterojunction. The porous heterostructures were prepared using the bottom-up combustion (BUC) approach. This method generated porous heterostructures by eliminating gaseous by-products. X-ray diffraction (XRD) optimization revealed that the ideal conditions included 1.00 g of polyvinyl alcohol (PVA), a synthesis temperature of 50 °C, and a 1 hour calcination time. Introducing copper (Cu) into the zinc oxide (ZnO) lattice caused a high-angle shift in the XRD pattern peaks. High-resolution transmission electron microscopy (HRTEM) images and XRD patterns confirmed the formation of Cu-doped ZnO/Ag/CuO (c-zac) heterostructures. Elemental mapping analysis confirmed the even surface distribution of Ag metal. The c-zac heterostructures exhibited superior optoelectrical and charge transfer properties compared to single ZnO. The heterostructures demonstrated improved methylene blue (MB) dye degradation potential ( = 0.065 min ) compared to single ZnO ( = 0.0041 min ). This photocatalytic potential is attributed to enhanced light absorption and charge transfer properties. The extended visible light absorption resulted from CuO and Ag's surface plasmon resonance properties. The selected 15c-zac heterostructure also performed well in a reusability photocatalytic test, remaining effective until the 3 cycle. Consequently, this heterostructure holds promise for scaling up as a catalyst for environmental remediation.