Construction of a stable radical hydrogen-bonded metal-organic framework with functionalized tetrathiafulvalene linkers
A stable two-dimensional radical hydrogen-bonded metal-organic framework, constructed using a modified tetrathiafulvalene-tetrabenzoate ((2-Me)-H 4 TTFTB) linker and Cd 2+ ions, exhibits a high electrical conductivity of 4.1 × 10 −4 S m −1 and excellent photothermal conversion with a temperature inc...
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Published in | Chemical communications (Cambridge, England) Vol. 6; no. 45; pp. 5812 - 5815 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
England
Royal Society of Chemistry
30.05.2024
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Subjects | |
Online Access | Get full text |
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Summary: | A stable two-dimensional radical hydrogen-bonded metal-organic framework, constructed using a modified tetrathiafulvalene-tetrabenzoate ((2-Me)-H
4
TTFTB) linker and Cd
2+
ions, exhibits a high electrical conductivity of 4.1 × 10
−4
S m
−1
and excellent photothermal conversion with a temperature increase of 137 °C in 15 s under the irradiation of a 0.7 W cm
−2
808 nm laser.
We have designed a radical hydrogen-bonded metal-organic framework with an atomically-resolved single crystal structure, demonstrating excellent stability, good electrical conductivity, and highly efficient near-infrared photothermal conversion. |
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Bibliography: | Electronic supplementary information (ESI) available. CCDC For ESI and crystallographic data in CIF or other electronic format see DOI https://doi.org/10.1039/d4cc01152j 2195767 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/d4cc01152j |