A convenient direct synthesis of alpha-N,N-dialkylaminophosphonates under aprotic conditions

A general one-pot synthesis of N,N-dialkylaminophosphonates under aprotic conditions is proposed using aromatic, heteroaromatic or aliphatic aldehydes and N,N-dialkyl-aminosilanes under trimethylsilyltriflate catalysis.

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Bibliographic Details
Published inPhosphorus and sulfur and the related elements Vol. 113; no. 1-4; pp. 299 - 301
Main Authors Malhiac, C, Combret, JC, Boussad, K, Klein, JL
Format Journal Article
LanguageEnglish
Published READING Taylor & Francis 01.06.1996
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Physical Sciences
Science & Technology
one-pot aprotic reaction
N,N-BIS(TRIMETHYLSILYL)METHOXYMETHYLAMINE
alpha-N,N-dialkylaminophosphonates
ACIDS
CH2NH2
dialkylaminosilanes
EQUIVALENT
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Summary:A general one-pot synthesis of N,N-dialkylaminophosphonates under aprotic conditions is proposed using aromatic, heteroaromatic or aliphatic aldehydes and N,N-dialkyl-aminosilanes under trimethylsilyltriflate catalysis.
ISSN:0308-664X
DOI:10.1080/10426509608046402