Efficient sulfur atom-doped three-dimensional porous MXene-assisted sodium ion batteries

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 53; no. 15; pp. 6583 - 6591
• Main Authors: Zhang, Linlin, Chen, Yiguang, Yu, Lianghao, Tao, Xin, Tang, Lan, Ye, Liangzheng, Liu, Yu, Han, Lu, Li, Hengzheng, Ling, Yihan, Zhu, Guang, Jin, Huile
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 16.04.2024
• Subjects: Anodes; Electrode materials; Energy storage; MXenes; Sodium; Sodium-ion batteries; Sulfur
• ISSN: 1477-9226; 1477-9234
• DOI: 10.1039/d3dt04312f

Recently, it has been reported that MXene is a promising pseudocapacitive material for energy storage, primarily due to its intercalation mechanism. However, Ti 3 C 2 T x MXenes face challenges, such as inadequate layer spacing and low specific capacity, which greatly hinder their potential as anode materials for sodium storage. In this study, MXene was doped with sulfur to create a three-dimensional porous structure that resulted in an increased layer spacing. The sulfur-doped porous MXene (SPM) demonstrated exceptional performance as sodium ion battery anodes, with a capacity of 335.2 mA h g −1 after 490 cycles at 2 A g −1 and a long-term cycling performance of 256.1 mA h g −1 even after 2480 cycles at 5 A g 1 . It is worth noting that the porous structure formed after sulfur-doping exhibits superior sodium storage performance compared to previously reported MXene-based electrodes. This highlights the feasibility of the structural construction strategy, offering an effective solution for energy storage and conversion applications. MXene doped with sulfur creates a 3D porous structure with increased layer spacing which demonstrated exceptional rate performance and good cycling stability as sodium ion battery anodes, with a long-term cycling performance of 256.1 mAh g −1 even after 2480 cycles at 5 A g −1 .