Synthesis of Poly(2-(cyclopent-2-en-1-yl)aniline) and Investigation of Its Electrophysical and Physicochemical Properties

A new electron donating polymer poly(2-(cyclopent-2-enyl)aniline) is synthesized, and synthesis parameters such as monomer-to-oxidant molar ratio and reaction duration are optimized. The separability of the target product (i.e., functionalized polyaniline) and its solubility in a series of conventio...

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Published inPhysics of the solid state Vol. 61; no. 11; pp. 2233 - 2240
Main Authors Biglova, Yu. N., Salikhov, R. B., Safargalin, I. N., Salikhov, T. R., Mustafin, A. G.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.11.2019
Springer Nature B.V
Subjects
ANILINE
CARRIER MOBILITY
CHARGE CARRIERS
Chemical synthesis
CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Current carriers
ELECTRIC CONDUCTIVITY
Electrical resistivity
MOLECULAR WEIGHT
MONOMERS
ORGANIC SOLVENTS
OXIDIZERS
Physics
Physics and Astronomy
Polarity
Polyanilines
POLYMERS
Solid State Physics
SOLUBILITY
SYNTHESIS
TEMPERATURE DEPENDENCE
THERMAL GRAVIMETRIC ANALYSIS
Thermogravimetry
thermogravimetry
polyaniline
morphology
electrical conductivity
thin films
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Summary:A new electron donating polymer poly(2-(cyclopent-2-enyl)aniline) is synthesized, and synthesis parameters such as monomer-to-oxidant molar ratio and reaction duration are optimized. The separability of the target product (i.e., functionalized polyaniline) and its solubility in a series of conventional organic solvents with different polarity are estimated. The synthesized high-molecular weight product is studied by thermogravimetry analysis, the temperature dependence of its electrical conductivity is investigated, and the charge carrier mobilities are calculated.
ISSN:1063-7834
1090-6460
DOI:10.1134/S1063783419110076