Halide-free deep eutectic solvents constructed from natural compounds for converting carbon dioxide to cyclic carbonate

Halide-free deep eutectic solvents (DESs) derived from natural biological compounds were used to gently catalyze the cycloaddition reaction between CO 2 and epoxides, with a TOF of 645 h −1 . The DFT calculation result was in good agreement with the experiment result, indicating that the ring closur...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 61; no. 16; pp. 3391 - 3394
Main Authors Yu, Wen-Wang, Meng, Xiang-Guang, Li, Wen, Zhou, Jie, Ma, Xian-Jian, Chu, Dan-Dan
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 18.02.2025
Royal Society of Chemistry
Subjects
Carbon dioxide
Chemistry
Chemistry, Multidisciplinary
Cycloaddition
Eutectic reactions
Physical Sciences
Science & Technology
Solvents
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Summary:Halide-free deep eutectic solvents (DESs) derived from natural biological compounds were used to gently catalyze the cycloaddition reaction between CO 2 and epoxides, with a TOF of 645 h −1 . The DFT calculation result was in good agreement with the experiment result, indicating that the ring closure process was the rate-determining step. Halide-free deep eutectic solvents (DESs) constructed from natural compounds were used to efficiently transform CO 2 into cyclic carbonates.
Bibliography:Electronic supplementary information (ESI) available. See DOI
https://doi.org/10.1039/d4cc06282e
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ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/d4cc06282e