Palladium complexes with ethylene-bridged bis( N-heterocyclic carbene) for C–C coupling reactions

A series of new ethylene-bridged bis(imidazolium) halides with various N-substitutions were synthesized. Complexation of these imidazolium halides with Pd(OAc) 2 produced new Pd(II) ethylene-bridged bis(carbene) complexes. Crystallographic analyses of some of the new imidazolium salts and Pd(II) com...

Full description

Saved in:
Bibliographic Details
Published inTetrahedron Vol. 60; no. 27; pp. 5807 - 5825
Main Authors Lee, Hon Man, Lu, Chi Ying, Chen, Chih Yuan, Chen, Wen Ling, Lin, Hung Ching, Chiu, Pei Ling, Cheng, Pi Yun
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 28.06.2004
Elsevier
Subjects
Chelating N-heterocyclic carbenes
Chemistry
Chemistry, Organic
C–C Coupling reactions
Palladium(II) complexes
Physical Sciences
Science & Technology
Chelating N-heterocyclic carbenes
C–C Coupling reactions
Palladium(II) complexes
chelating N-heterocyclic carbenes
LIGANDS
C-C coupling reactions
BIDENTATE
TRANSFER HYDROGENATION
SYSTEMS
palladium(II) complexes
N-HETEROCYCLIC CARBENES
IMIDAZOLES
ARYLBORONIC ACIDS
ARYL CHLORIDES
CATALYSTS
Online AccessGet full text

Cover

More Information
Summary:A series of new ethylene-bridged bis(imidazolium) halides with various N-substitutions were synthesized. Complexation of these imidazolium halides with Pd(OAc) 2 produced new Pd(II) ethylene-bridged bis(carbene) complexes. Crystallographic analyses of some of the new imidazolium salts and Pd(II) complexes were determined. Applications of these seven-member palladacycles in Suzuki and Heck coupling reactions produced comparable catalytic activities to those of six-member analogs. Graphic
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2004.04.070