Tetraphenylethene–diyne hybrid nanoparticles from Glaser-type dispersion polymerization

Organic-based nanoparticles hold great potential for optoelectronics and biomedicine as they may provide optical properties in the visible range and notable advantages over inorganic counterparts. In this report, we exploit aggregation-induced emission (AIE) from the well-known tetraphenylethene (TP...

Full description

Saved in:
Bibliographic Details
Published inRSC advances Vol. 7; no. 57; pp. 36132 - 36137
Main Authors Picard-Lafond, Audrey, Daigle, Maxime, Morin, Jean-François
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 2017
Subjects
Chemical synthesis
Emission
Hybrid systems
Irradiation
Morphology
Nanoparticles
NMR
Nuclear magnetic resonance
Optical properties
Optoelectronics
Organic chemistry
Photoluminescence
Polydispersity
Polymerization
Structural analysis
Ultraviolet radiation
Online AccessGet full text

Cover

More Information
Summary:Organic-based nanoparticles hold great potential for optoelectronics and biomedicine as they may provide optical properties in the visible range and notable advantages over inorganic counterparts. In this report, we exploit aggregation-induced emission (AIE) from the well-known tetraphenylethene (TPE) to yield photoluminescent polymer particles by a dispersion polymerization route. 1,1-Bis(4-ethynylphenyl)-2,2-diphenylethene is polymerized by a Glaser-type dispersion polymerization, providing nanoparticles of 170–600 nm with low polydispersity by simply varying monomer loadings. Optical characterization reveals emission bands at 500 nm and 600 nm, where UV irradiation of the particles causes the 500 nm band to increase relative to the 600 nm one. Structural characterization by 13 C MAS-NMR allows confirming that this change upon UV irradiation is not induced by a chemical modification, thus suggesting a physical change in the particle's morphology. Altogether, the results of this work allow enlarging the library of TPE-comprising particles, but also enhance the variety of particles synthesized from Glaser-type dispersion polymerization. The study also allows gaining insight into the photochemical stability of TPE-containing particles, where the non-destructive UV irradiation lets us plan the development of new polyyne/TPE hybrid systems.
ISSN:2046-2069
2046-2069
DOI:10.1039/C7RA04513A