Chloro­(diethyl­amino)­tris(μ‐diethyl­carbamato)­dizinc(II): an example of the generality of the threefold paddlewheel structure in carbamatozinc chemistry

The title complex, [Zn2(C5H10NO2)3Cl(C4H11N)] or [Zn2{O2CN(C2H5)2}3Cl{HN(C2H5)2}], consists of a dinuclear Zn2(O2CNEt2)3+ core bridged by three diethyl­carbamate ligands in a μ1,3 manner and capped by chloride and diethyl­amine ligands. This threefold paddlewheel structure is common in carbamatozinc...

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Published inActa crystallographica. Section E, Structure reports online Vol. 60; no. 3; pp. m285 - m287
Main Authors McCowan, C. Shawn, Buss, Carrie E., Young Jr, Victor G., McDonnell, Ryan L., Caudle, M. Tyler
Format Journal Article
LanguageEnglish
Published 5 Abbey Square, Chester, Cheshire CH1 2HU, England Munksgaard International Publishers 01.03.2004
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Summary:The title complex, [Zn2(C5H10NO2)3Cl(C4H11N)] or [Zn2{O2CN(C2H5)2}3Cl{HN(C2H5)2}], consists of a dinuclear Zn2(O2CNEt2)3+ core bridged by three diethyl­carbamate ligands in a μ1,3 manner and capped by chloride and diethyl­amine ligands. This threefold paddlewheel structure is common in carbamatozinc coordination chemistry.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536804002193