Aquabis(1,10‐phenanthroline‐κ2N,N′)[2,4,6‐tris(4‐sulfonatophenylamino)‐1,3,5‐triazin‐1‐ium‐κO]nickel(II) dihydrate

In the title complex, [Ni(C21H16N6O9S3)(C12H8N2)2(H2O)]·2H2O or [Ni(HTST)(phen)2(H2O)]·2H2O, where H3TST is 2,4,6‐tris(4‐sulfophenylamino)‐1,3,5‐triazine and phen is phenanthroline, the NiII ion is in a distorted octahedral coordination environment defined by four N atoms from two phen ligands, one...

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Bibliographic Details
Published inActa crystallographica. Section E, Structure reports online Vol. 63; no. 8; p. m2119
Main Authors Yu, Yun‐Fang, Wei, Yong‐Qin, Wu, Ke‐Chen
Format Journal Article
LanguageEnglish
Published 5 Abbey Square, Chester, Cheshire CH1 2HU, England Blackwell Publishing Ltd 01.08.2007
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Summary:In the title complex, [Ni(C21H16N6O9S3)(C12H8N2)2(H2O)]·2H2O or [Ni(HTST)(phen)2(H2O)]·2H2O, where H3TST is 2,4,6‐tris(4‐sulfophenylamino)‐1,3,5‐triazine and phen is phenanthroline, the NiII ion is in a distorted octahedral coordination environment defined by four N atoms from two phen ligands, one O atom from an aqua ligand and one O atom from the SO3 group of an HTST ligand. In the crystal structure, intermolecular N—H...O and O—H...O hydrogen bonds connect molecules to form a two‐dimensional network.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536807033223