Bis[(2,3,6,7,12,13,16,17‐octa­ethyl­porphycenato)oxomolybdenum(V)] hexamolybdate(VI)

The title compound, [Mo(C36H44N4)O]2[Mo6O19], contains a five‐coordinate molybdenum–porphycene cationic complex, accompanied by a centrosymmetric hexa­molybdate counter‐anion. This is the first structure for a molybdenum porphycene. The shape of the central N4 cavity is recta­ngular, enlarged length...

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Published inActa crystallographica. Section E, Structure reports online Vol. 62; no. 6; pp. m1272 - m1274
Main Authors Maeda, Daisuke, Aritome, Isao, Shimakoshi, Hisashi, Hisaeda, Yoshio
Format Journal Article
LanguageEnglish
Published 5 Abbey Square, Chester, Cheshire CH1 2HU, England Blackwell Publishing Ltd 01.06.2006
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Summary:The title compound, [Mo(C36H44N4)O]2[Mo6O19], contains a five‐coordinate molybdenum–porphycene cationic complex, accompanied by a centrosymmetric hexa­molybdate counter‐anion. This is the first structure for a molybdenum porphycene. The shape of the central N4 cavity is recta­ngular, enlarged lengthwise by metal coordination, and the mean short and long N⋯N distances defining the N4 cavity are 2.582 (9) and 3.031 (9) Å, respectively.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536806016461