Bis[(2,3,6,7,12,13,16,17‐octaethylporphycenato)oxomolybdenum(V)] hexamolybdate(VI)
The title compound, [Mo(C36H44N4)O]2[Mo6O19], contains a five‐coordinate molybdenum–porphycene cationic complex, accompanied by a centrosymmetric hexamolybdate counter‐anion. This is the first structure for a molybdenum porphycene. The shape of the central N4 cavity is rectangular, enlarged length...
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Published in | Acta crystallographica. Section E, Structure reports online Vol. 62; no. 6; pp. m1272 - m1274 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
5 Abbey Square, Chester, Cheshire CH1 2HU, England
Blackwell Publishing Ltd
01.06.2006
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Online Access | Get full text |
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Summary: | The title compound, [Mo(C36H44N4)O]2[Mo6O19], contains a five‐coordinate molybdenum–porphycene cationic complex, accompanied by a centrosymmetric hexamolybdate counter‐anion. This is the first structure for a molybdenum porphycene. The shape of the central N4 cavity is rectangular, enlarged lengthwise by metal coordination, and the mean short and long N⋯N distances defining the N4 cavity are 2.582 (9) and 3.031 (9) Å, respectively. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536806016461 |