Acetonitrile{2‐[3‐(dimethylamino)propyliminomethyl]‐4‐nitrophenolato‐κ3N,N′,O}(thiocyanato‐κN)copper(II)
In the title mononuclear copper(II) complex, [Cu(C12H16N3O3)(NCS)(C2H3N)], the CuII atom is five‐coordinated in a square‐pyramidal geometry, with one O and two N atoms of the Schiff‐base ligand and one N atom of the thiocyanate ligand defining the basal plane. The apical position is occupied by the...
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Published in | Acta crystallographica. Section E, Structure reports online Vol. 63; no. 7; p. m1837 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
5 Abbey Square, Chester, Cheshire CH1 2HU, England
Blackwell Publishing Ltd
01.07.2007
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Online Access | Get full text |
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Summary: | In the title mononuclear copper(II) complex, [Cu(C12H16N3O3)(NCS)(C2H3N)], the CuII atom is five‐coordinated in a square‐pyramidal geometry, with one O and two N atoms of the Schiff‐base ligand and one N atom of the thiocyanate ligand defining the basal plane. The apical position is occupied by the N atom of the acetonitrile molecule. The structure is stabilized by intramolecular C—H...N and intermolecular C—H...O hydrogen‐bonding interactions. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536807025342 |