(+)‐6‐Benzyl‐17‐oxosparteine

The title compound, C22H30N2O, was prepared from (−)‐17‐oxosparteine. The lactam N atom is essentially planar, lying 0.0150 (12) Å out of the plane of its three bonded C atoms, and the C=O distance is 1.2315 (13) Å. The conformation of the sparteine ring system is nearly identical to that of 17‐oxos...

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Published inActa crystallographica. Section E, Structure reports online Vol. 59; no. 11; pp. o1832 - o1834
Main Authors Gadepalli, Rama Sarma V. S., Murty, Madugula S. R., Slauson, Stephen R., Rimoldi, John M., Fronczek, Frank R.
Format Journal Article
LanguageEnglish
Published 5 Abbey Square, Chester, Cheshire CH1 2HU, England Munksgaard International Publishers 01.11.2003
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Summary:The title compound, C22H30N2O, was prepared from (−)‐17‐oxosparteine. The lactam N atom is essentially planar, lying 0.0150 (12) Å out of the plane of its three bonded C atoms, and the C=O distance is 1.2315 (13) Å. The conformation of the sparteine ring system is nearly identical to that of 17‐oxosparteine.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536803023808