Synthesis and Characterization of Pyridino(1,4‐ Η ‐cyclohexa‐1,3‐diene)Derivatives of Iron Tricarbonyl Complexes

In this synthesis, we have been able to show that, the addition of x‐ substituted pyridines, (X = H, 2‐ Me, 3‐ Me 4‐ Me, 4‐NH 2 and 4‐N(CH 3 ) 2 to the dienyl ring of the organometallic cation, [(Fe(CO) 3 (1‐5‐ η ‐2‐Me0C 3 H 6 )]BF 4 and [(Fe(CO) 3 (1‐5‐ η ‐C 6 H 7 )]BF 4 gives ionic substituted die...

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Bibliographic Details
Published inE-journal of chemistry Vol. 8; no. 3; pp. 960 - 965
Main Authors Odiaka, T. I., Akinyele, O. F., Adejoro, I. A.
Format Journal Article
LanguageEnglish
Published Hindawi Limited 2011
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Summary:In this synthesis, we have been able to show that, the addition of x‐ substituted pyridines, (X = H, 2‐ Me, 3‐ Me 4‐ Me, 4‐NH 2 and 4‐N(CH 3 ) 2 to the dienyl ring of the organometallic cation, [(Fe(CO) 3 (1‐5‐ η ‐2‐Me0C 3 H 6 )]BF 4 and [(Fe(CO) 3 (1‐5‐ η ‐C 6 H 7 )]BF 4 gives ionic substituted diene products, (X C 5 H 4 ‐C 6 H 6 Y (Fe(CO) 3 ] BF 4 ,Y=H or 2‐MeO. The reaction takes place at ordinary room temperature. The resulting products were isolated and characterized.
ISSN:2090-9063
0973-4945
2090-9071
2090-9810
DOI:10.1155/2011/781484