Synthesis and stereochemistry of bis(dithiacrown ether) and dodecylthio substituted (E)-thiodesaurines

Reductive dimerization of dodecylthio substituted 1,2-dithiole-3-thiones 6a-b and trithion-dithiacrown ethers 10a-c with triethyl phosphite furnished bis- and tetrakis (dodecylthio), and bis(dithiacrown ether) substituted thiodesaurines (E)-11a-b and (E)-12a-c. The stereochemistry of bis(dithia[15]c...

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Published inJournal für praktische Chemie, Chemiker-Zeitung Vol. 340; no. 5; pp. 450 - 454
Main Authors Rudershausen, S, Drexler, HJ, Holdt, HJ
Format Journal Article
LanguageEnglish
Published BERLIN Wiley 01.01.1998
Subjects
Chemistry
Chemistry, Applied
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
CARBON-DISULFIDE
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Summary:Reductive dimerization of dodecylthio substituted 1,2-dithiole-3-thiones 6a-b and trithion-dithiacrown ethers 10a-c with triethyl phosphite furnished bis- and tetrakis (dodecylthio), and bis(dithiacrown ether) substituted thiodesaurines (E)-11a-b and (E)-12a-c. The stereochemistry of bis(dithia[15]crown-5)-thiodesaurine (E)-12b has been determined by X-ray crystallographic analysis.
ISSN:0941-1216
DOI:10.1002/prac.19983400507