Reaction of 1,3-Dithiane with Trifluoromethylthiocopper

The 1,3-dithiane ring undergoes cleavage even under mild neutral reaction conditions when heated in the presence of trifluoromethylthiocopper. The free-radical nature of the reaction was confirmed by the characterization of bis-(trifluoromethyl)disulfide as one of the products.

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Bibliographic Details
Published inPhosphorus, sulfur, and silicon and the related elements Vol. 181; no. 1; pp. 105 - 112
Main Authors Munavalli, S., Rohrbaugh, D. K., Rossman, D. I., Durst, H. D.
Format Journal Article
LanguageEnglish
Published ABINGDON Taylor & Francis Group 01.01.2006
Taylor & Francis
Subjects
1,3-dithialane
1,3-dithiane
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
free-radical reactions
Physical Sciences
ring cleavage products
Science & Technology
trifluoromethylthiocopper
REAGENTS
1,3-dithiane
SULFIDES
MASS-SPECTRA
TRIFLUOROMETHYLSULFENYL CHLORIDE
1,3-dithialane
CARBANIONS
free-radical reactions
FRAGMENTATION
CLEAVAGE
ELECTRON-IMPACT
trifluoromethylthiocopper
ring cleavage products
BIS-1,3-DITHIOLANES
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Summary:The 1,3-dithiane ring undergoes cleavage even under mild neutral reaction conditions when heated in the presence of trifluoromethylthiocopper. The free-radical nature of the reaction was confirmed by the characterization of bis-(trifluoromethyl)disulfide as one of the products.
ISSN:1042-6507
1563-5325
DOI:10.1080/104265090969027